Hostname: page-component-78c5997874-v9fdk Total loading time: 0 Render date: 2024-11-03T00:26:57.253Z Has data issue: false hasContentIssue false

Mechanism of Intermetallic Phase Formation in thin Liquidsolid Diffusion Couples

Published online by Cambridge University Press:  21 February 2011

F. Bartels
Affiliation:
Max-Planck-Institut für Metaliforschung, Seestr. 75, D-7000 Stuttgart 1, Germany
T. Muschik
Affiliation:
Max-Planck-Institut für Metaliforschung, Seestr. 75, D-7000 Stuttgart 1, Germany
W. Gust
Affiliation:
Max-Planck-Institut für Metaliforschung, Seestr. 75, D-7000 Stuttgart 1, Germany
Get access

Abstract

Thin interconnection layers entirely consisting of intermetallic phases have been produced by joining planar Cu substrates coated with thin films of Sn. The thin layers of intermetallic phases are produced at low temperatures (<300°C) and short reaction times (5-120 s) in a process similar to reflow soldering by a liquid-solid reaction between Sn and Cu. Metallographic methods and X-ray analysis have been used to characterize the initial stages of the formation of the intermetallic phases. The reaction to form intermetallic phases via Cu dissolution and diffusion in the liquid Sn is very fast in the first 10-15 s when the liquid Sn is in contact with the Cu substrate along channels of liquid Sn between grains of the intermetallic phases. The stability of these narrow channels of liquid Sn is discussed in terms of the wettability of different types of grain boundaries in the textured layer of intermetallic phases.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

LITERATURE

[1] Thwaites, C.J., Int. Met. Rev. 17 (1972) 249.CrossRefGoogle Scholar
[2] Frear, D., Griva, D., Morris, J. W. Jr., J. Elec. Mat. 16 (1987) 181.CrossRefGoogle Scholar
[3] Massalski, T.B. et al. (eds.), Binary Alloy Phase Diagrams, ASM International, Materials Park, Ohio (1990).Google Scholar
[4] Bartels, F., Gust, W., Muschik, T., DVS-Berichte 141 (1992) 22.Google Scholar
[5] Bartels, F., Ph.D. thesis, Univ. of Stuttgart (1993).Google Scholar
[6] Gangulee, A., Das, C.C., Bever, M.B., Met. Trans. 4 (1973) 2063.CrossRefGoogle Scholar