Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-19T02:13:15.953Z Has data issue: false hasContentIssue false

Mechanical Response of Diamond at Nanometer Scaes: Diamond Polishing and Atomic Force Microscopy

Published online by Cambridge University Press:  17 March 2011

Ruben Pérez
Affiliation:
Departmento de Física Teórica de la Materia Condensada, Universidad Autónoma de Madrid, E-28049 Madrid, Spain
Murray R. Jarvis
Affiliation:
Theory of Condensed Matter, Cavendish Laboratory, University of Cambridge, Madingley Rad, Cambridge CB3 OHE, United Kingdom
Michael C. Payne
Affiliation:
Theory of Condensed Matter, Cavendish Laboratory, University of Cambridge, Madingley Rad, Cambridge CB3 OHE, United Kingdom
Get access

Abstract

Total energy pseudopotential methods are used to study two different processes involving the mechanical interaction of diamond nanoasperities and diamond surfaces: the wear processes reponsible for diamond polishing, an the mechanical deformation of tip and surface during the operation of the Atomic Force Microscope in contact Mode (CM-AFM). The strong asymmetry in the rate of polishing between different dirctions onthe diamond (110) surface is explained in terms of on atomistic mechanism for nano-groove formation. The pst–polishing surface morphology and the nature of the polishing residue epredicted by this mechanism are consistent with experimental evidence. In the case of CM-FAM, our calculations show that a tip terminated in a single atom is able to sustain forces in excess of 30 nN. The magnitude of the normal force was unexpectedlyfound to be verye similar for th approach on top of an atom or on a hollow position on the surface. This behaviour is due to tip relaxations induced by the interaction with the surface. These forces are also rather insensitive to the chemical nature of the tip apex.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Payne, M.C. et al. , Rev. Mod. Phys. 64, 1045 (1992).Google Scholar
2. Hitchiner, M.P., Wilks, E.M. and Wilks, J., Wear, 94, 103, (1984).Google Scholar
3. Wilks, E.M. and Wilks, J., J. Phys.l D5, 1902, (1972)Google Scholar
4. Couto, M. et al. Appl. Surf. Sci. 62, 264 (1992); J. Hard Mater. 5, 31 (1994).Google Scholar
5. Wilks, E.M. and Wilks, J., Properties and Applications of Diamond (Kluwer, Dordrecht, 1992), p. 348.Google Scholar
6. Grillo, S.E. and Field, J.E., J. Phys. D30, 202, (1997).Google Scholar
7. Bouwelen, F.M. van, PhD Thesis, University of Cambridge (1996).Google Scholar
8. Jarvis, M.R., Pérez, R., Bouwelen, F.M. van and Payne, M.C.. Phys. Rev. Lett. 80, 3428 (1998).Google Scholar
9. Pérez, R., Jarvis, M.R. and Payne, M.C., (to be published)Google Scholar
10. Binnig, G., Rohrer, H., Gerner, C. and Weibel, E., Phys. Rev. Lett. 49, 57, (1982)Google Scholar
11. Jarvis, M.R., PhD Thesis, University of Cambridge (1998).Google Scholar
12. Gogotsi, Y.G., Kailer, A. and Nickel, K.G., Nature (London) 401, 664 (1994).Google Scholar
13. Chacham, H. and Kleinman, L., Phys. Rev. Lett. 85, 4904 (2000)Google Scholar
14. Ke, S.H. et al. , Rev. Phys. Rev. B60, 11639 (1999).Google Scholar
15. Tobik, J., Stich, I., Pérez, R. and Terekura, K., Phys. Rev. Lett. B60, 11639 (1999)Google Scholar
16. Jarvis, M.R., Pérez, R. and Payne, M.C., Phys. Rev. Lett. 86, 1287 (2001).Google Scholar