Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-27T02:11:16.448Z Has data issue: false hasContentIssue false

Mechanical Behavior of Polymer Nanocomposites: a discrete simulation approach

Published online by Cambridge University Press:  11 February 2011

E. Chabert
Affiliation:
GEMPPM-INSA Lyon, 7 Avenue Capelle, 69621 Villeurbanne Cedex
C. Gauthier
Affiliation:
GEMPPM-INSA Lyon, 7 Avenue Capelle, 69621 Villeurbanne Cedex
R. Dendievel
Affiliation:
GPM2-INPG, 101 Rue de la Piscine, 38402 Saint Martin d'Hères Cedex
L. Chazeau
Affiliation:
GEMPPM-INSA Lyon, 7 Avenue Capelle, 69621 Villeurbanne Cedex
J.-Y. Cavaillé
Affiliation:
GEMPPM-INSA Lyon, 7 Avenue Capelle, 69621 Villeurbanne Cedex
Get access

Abstract

This work reports the dynamic mechanical characterization of nanocomposites based on a poly(butyl acrylate) matrix filled with spherical particles of either polystyrene or silica both of diameter around 100 nm. A discrete numerical simulation, taking into account the microstructure and the nature of contact between reinforcing particles has been developed. This simulation enables to quantify the effect of interactions between filler particles on the elastic modulus, and in a more general sense, to clarify the concept of mechanical percolation. It gives results in very good agreement with experimental data.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Giannelis, E.P., Adv. Mater. 8, 29 (1996)Google Scholar
[2] Chazeau, L., Gauthier, C., Vigier, G., Cavaillé, J.Y., in “Handbook of Organic-Inorganic Hybrids Materials and nanocomposites” edited by Nalwa, H.S., American Scientific Publishers, (2003)Google Scholar
[3] Stöber, W., Fink, A., Bohn, E., J. Colloid Interf. Sci., 26, 62 (1968).Google Scholar
[4] Etienne, S., Cavaillé, J.Y., Perez, J., Rev. Sci. Instrum. 53–8, 1261 (1992)Google Scholar
[5] Chabert, E., Dendievel, R., Gauthier, C. and Cavaillé, J.-Y., submitted to Compos. Sci. Technol‥ Google Scholar
[6] Jagota, A. and Sherer, G. W., J. Am. Chem. Soc. 78, 521 (1995).Google Scholar