Hostname: page-component-78c5997874-94fs2 Total loading time: 0 Render date: 2024-11-19T02:03:33.003Z Has data issue: false hasContentIssue false

Magnetic Properties of Organic Ferromagnetic TDAE-C60 Single Crystals and Thin Films

Published online by Cambridge University Press:  10 February 2011

M. Tokumoto
Affiliation:
Electrotechnical Laboratory, Tsukuba, Ibaraki 305, Japan
Y. Tsubaki
Affiliation:
Science University of Tokyo, Noda, Chiba 278, Japan
K. Pokhodnya
Affiliation:
Jozef Stefan Institute, Jamova 39, Ljubljana, Slovenia
Y. sakakibara
Affiliation:
Electrotechnical Laboratory, Tsukuba, Ibaraki 305, Japan
A. Omerzu
Affiliation:
Jozef Stefan Institute, Jamova 39, Ljubljana, Slovenia
D. Mihailovic
Affiliation:
Jozef Stefan Institute, Jamova 39, Ljubljana, Slovenia
T. Uchida
Affiliation:
Science University of Tokyo, Noda, Chiba 278, Japan
Get access

Abstract

Recent progress in the study on magnetic properties of molecular soft ferromagnet TDAE-C60 (where TDAE is tetrakis(dimethylamino) ethylene) is reported. Both crystalline and thin film samples are prepared by the diffusion method and the temperature and field dependence of magnetization are studied by SQUID magnetometer. The magnetic behaviors of single crystals were found to vary from sample to sample. In best single crystals, the saturation magnetization as high as 1.0 μB/C60 has been observed. Spontaneous magnetization and its temperature dependence was evaluated from the Arrott plot. The ferromagnetic phase transition was also observed in TDAE-C60 thin films.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Allemand, P.M., Khemani, K., Koch, A., Wudl, F., Holczer, K., Donovan, S., Gruner, G., Tompson, J.D.: Science 253 (1991) 301.Google Scholar
2. Suzuki, A., Suzuki, T. and Maruyama, Y.: Solid State Commun. 96 (1995) 253.Google Scholar
3. Blinc, R., Pokhodnia, K., Cevc, P., Arcon, D., Omerzu, A., Mihailovic, D., Venturini, P., Golic, L., Trontelj, Z., Luznik, J., Jeglicic, Z. and Pinat, J.: Phys. Rev. Lett. 76 (1996) 523.Google Scholar
4. Tokumoto, M., Tanaka, K., Sato, T., Yamabe, T., Omerzu, A., Pokhodnia, K. and Mihailovic, D. in Proc. Int. Winterschool on Electronic Properties of Novel Materials “Fullerenes and Fullerene Nanostructures” Kirchberg, Austria, 1996, ed. Kuzmany, H. et al. (World Scientific, 1996) p.535.Google Scholar
5. Tokumoto, M., Song, Y.S., Tanaka, K., Sato, T., Yamabe, T., Omerzu, A., Pokhodnia, K. and Mihailovic, D.: Synthetic Metals 86 (1997) 2315.Google Scholar
6. Jaglicic, Z., Trontelj, Z., Luznik, J., Pirnat, J., Blinc, R.: Solid State Commun. 101 (1997) 591.Google Scholar
7. Mihailovic, D., Venturini, P., Hassanien, A., Gasperic, J., Lutar, K., Milicev, S., Srdanov, V. in Proc. Euroconference on Fullerides and Fulleroides, Kirchberg. Austria, 1994, ed. Kuzmany, H. et al. (Springer-Verlag, 1994) p.275.Google Scholar
8. Bommeli, F., Degiorgi, L., Wachter, P., Mohailovic, D., Hassanien, A., Venturini, P., Schreiber, M. and Diederich, F.: Phys. Rev. B 51 (1995) 1366.Google Scholar
9. Hassanien, A., Musevic, I., Mihailovic, D., Omerzu, A. and Tomic, S. in Proc. Int. Winterschool on Electronic Properties of Novel Materials “Physics and Chemistry of Fullerenes and Derivatives”, Kirchberg, Austria, 1995, ed.Kuzmany, H. et al. (World Scientific, 1995) p.489.Google Scholar
10. Tokumoto, M., Song, Y.S., Tanaka, K., Sato, T., Yamabe, T.: Solid State Commun. 97 (1996) 349.Google Scholar
11. Arrott, A.: Phys. Rev. 108 (1957) 1394.Google Scholar