Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-29T09:46:23.388Z Has data issue: false hasContentIssue false

The Lithium Electrode Interface: A Crucial Aspect in Polymer Batteries

Published online by Cambridge University Press:  25 February 2011

Bruno Scrosati
Affiliation:
Dipartimento di Chimica, Università di Roma ‘La Sapienza’00185 Rome, Italy
Fausto Croce
Affiliation:
Dipartimento di Chimica, Università di Roma ‘La Sapienza’00185 Rome, Italy
Get access

Abstract

Rechargeable, polymer lithium batteries are today considered as very promising advanced power sources for electric vehicle and/or consumer electronics. Many polymer electrolytes, some of which having very high ambient temperature conductivity, have been developed and characterized. However, very little attention has been so far dedicated to the study of the characteristics of the lithium electrode interface. Since the clarification of the interfacial phenomena is crucial in assessing the effective impact of polymer batteries, we have undertaken a detailed investigation of the Li passivation processes in most relevant electrolyte media and in this work we report results obtained in highly conductive cells using electrolytes formed by the immobilization of lithium solvates in polymer networks.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1) Gray, F.M. Solid Polymer Electrolytes, (VCH, Publishers, Inc., New York, N.Y. 1991).Google Scholar
2) Scrosati, B., Applications of Electroactive Polymers, (Chapman and Hall ltd., London, 1993).Google Scholar
3) Abraham, R.M. and Alamgir, M., Proceedings of the 35th Intl. Power Sources Symp. (IEEE Customer Service, Piscatawav N.J. 1992) p. 264.Google Scholar
4) Polymer Electrolyte Reviews 1 and 2, MacCallum, J. and Vincent, C.A. Eds, (Elsevier Applied Science, London, 1987 and 1989).Google Scholar
5) Croce, F., Gerace, F. and Scrosati, B., as in ref. 3, p. 267.Google Scholar
6) Croce, F. and Scrosati, B., J. Power Sources, (in press).Google Scholar
7) Abraham, K.M. and Alamgir, M.J., J. Electrochem. Soc., 1–36, 1657 (1990).Google Scholar
8) Abraham, K.M. and Alamgir, M.J., Jones, G.S. and Wu, L., Electrochem. Soc, Fall Meeting Phoenix AZ, Oct. 13-17, 1991, abstr. 691.Google Scholar
9) Abraham, K.M. and Alamgir, M.J., 6th Intl. Meeting on Lithium Batteries, IMLB-6, Munster, Germany, May 10-15, 1992, abstr. THU-01.Google Scholar