Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-29T07:42:18.979Z Has data issue: false hasContentIssue false
  • English
  • Français

Line Tension Effect on Alkane Droplets Near the Wetting Transition

Published online by Cambridge University Press:  10 February 2011

A. D. Dussaud  and
M. Vignes-Adler
A. D. Dussaud
Affiliation:
Department of Chemical Engineering, Princeton University, Princeton NJ 08544
M. Vignes-Adler
Affiliation:
Laboratoire des Phénomènes de Transport dans les Mélanges du CNRS SP2MI, Bd 3 Téléport 2, BP 179, F-86960 Futuroscope Cedex, France
Get access

Abstract

We have investigated n-octane droplets resting on the surface of sodium chloride solutions as a function of the salt concentration in a saturated, closed cell. For high salt concentration, the system approaches a wetting transition : the contact angles are very small (∼ 1°), the macroscopic droplet is unstable, and it breaks up spontaneously into microdroplets. The stable polydisperse population of microdroplets (5 μm < r < 250 μm) allowed us to analyze the dependence of the contact angle on droplet size. Because of the low contact angle values, accurate measurement ofcontact angles was obtained by interferometry. Moreover the accuracy of the classical method was significantly improved through the systematic use of three wavelengths. The relationship between the contact angle and the size droplet size indicated a positive line tension, τ, and the order of magnitude of τ was in good agreement with the theoretical prediction, τ, varies between (8.6 ± 0.9). 10−11 N and (1 ± 0.1).10−9 N and was dependent on the salt concentration. The positive sign of τ and its significant effect on droplet shape were related to the fact that the system was approaching the wetting transition.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 464: Symposium FF – Dynamics in Small Confining Systems III , 1996 , 287
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. De Feijter, J.A. and Vrij, A., J. Electroanal. Chem. 37, p. 9 (1972).Google Scholar
2. Toshev, B.V., Platikanov, D. and Scheludko, A., Langmuir 4, p. 489 (1988).Google Scholar
3. Widom, B., J. Phys. Chem. 99, p. 2803 (1995).Google Scholar
4. Aveyard, R. R., and Clint, J. H., J. Chem. Soc., Faraday Trans. 92(1), p. 85 (1996).Google Scholar
5. Alexandrov, A. D., Toshev, B. and Sheludko, A. D., Colloids and Surfaces A. 79, p. 43 (1993).Google Scholar
6. Rowlinson, J. S. and Widom, B. in Molecular Theory of Capillarity. Clarendon Press, Oxford, 1984 p. 240.Google Scholar
7. Indekeu, J. O., Int. J. Modern Phys. B. 8, p.309 (1994).Google Scholar
8. Dussaud, A. D. and Vignes-Adler, M., Langmuir, in press.Google Scholar
9. Bikerman, J.J. in Physical Surfaces. Academic Press, New York, 1970.Google Scholar
10. Pujado, P.R., Scriven, L. E., J. Colloid Interface Sci. 40, p. 82 (1972).Google Scholar
11. Ross, S. and Morrison, I.D. in Colloidal Systems and Interfaces. John Wiley & Sons, New-York, 1988.Google Scholar
12. Kerins, J. and Widom, B., J. Chem. Phys. 77, p. 2061 (1982).Google Scholar
13. Churaev, N. V., Starov, V. M. and Derjaguin, B. V., J. Colloid Interface Sci. 89, 1, p. 16 (1982).Google Scholar