Hostname: page-component-586b7cd67f-2plfb Total loading time: 0 Render date: 2024-11-29T09:18:08.957Z Has data issue: false hasContentIssue false

Light-Induced Enhancement of Rectification by Monolayer of Hexadecylquinolinium Tricyanoquinodimethanide Between Al Electrodes

Published online by Cambridge University Press:  21 March 2011

Tao Xu
Affiliation:
Laboratory for Molecular Electronics, Chemistry Department, The University of Alabama Tuscaloosa, AL 35487-0336
Robert M. Metzger
Affiliation:
Laboratory for Molecular Electronics, Chemistry Department, The University of Alabama Tuscaloosa, AL 35487-0336
Get access

Abstract

Photoinduced changes in electrical rectification were measured for a 5-layer Langmuir-Blodgett multilayer of hexadecylquinolinium tricyanoquinodimethanide, sandwiched between opaque and semitransparent Al electrodes, as a function of bias and wavelength. The current increases with the light intensity, but this may be simply due to heating of the sample, rather than to a photon-induced enhancement of the rectification.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Ashwell, G. J., Sambles, J. R., Martin, A. S., Parker, W. G., and Szablewski, M., J. Chem. Soc. Chem. Comm. 1374 (1990).Google Scholar
2. Martin, A. S., Sambles, J. R. and Ashwell, G. J., Phys. Rev. Lett. 70, 218 (1993).Google Scholar
3. Metzger, R. M., Chen, B., Höpfner, U., Lakshmikantham, M. V., Vuillaume, D., Kawai, T., Wu, X., Tachibana, H., Hughes, T. V., Sakurai, H., Baldwin, J. W., Hosch, C., Cava, M. P., Brehmer, L., and Ashwell, G. J., J. Am. Chem. Soc. 119, 10455 (1997).Google Scholar
4. Vuillaume, D., Chen, B., and Metzger, R. M., Langmuir 15, 4011 (1999).Google Scholar
5. Chen, B. and Metzger, R. M., J. Phys. Chem. B103, 4447 (1999).Google Scholar
6. Baldwin, J. W., Chen, B., Street, S. C., Konovalov, V. V., Sakurai, H., Hughes, T. V., Simpson, C. S., Lakshmikantham, M. V., Cava, M. P., Kispert, L. D., and Metzger, R. M., J. Phys. Chem. B103, 4269 (1999).Google Scholar
7. Metzger, R. M., J. Mater. Chem. 9, 2027 (1999).Google Scholar
8. Metzger, R. M., Acc. Chem. Res. 32, 950 (1999).Google Scholar
9. Metzger, R. M., J. Mater. Chem. 10, 55 (2000).Google Scholar
10. Fujihira, M., Nishiyama, K., and Yamada, H., Thin Solid Films 132, 77 (1986).Google Scholar