Hostname: page-component-586b7cd67f-r5fsc Total loading time: 0 Render date: 2024-11-20T07:02:48.723Z Has data issue: false hasContentIssue false

Layer-by-Layer Thin Films of Carbon Nanotubes

Published online by Cambridge University Press:  26 February 2011

Marco Palumbo
Affiliation:
[email protected], Durham University, School of Engineering, South Road, Durham, N/A, DH1 3LE, United Kingdom, +44 (0)191 334 2535, +44 (0)191 334 2407
Kye Ung Lee
Affiliation:
[email protected], Korea Advanced Institute, Department of Materials Science and Engineering, Korea, Republic of
Byung Tae Ahn
Affiliation:
[email protected], Korea Advanced Institute, Department of Materials Science and Engineering, Korea, Republic of
Anil Suri
Affiliation:
[email protected], Durham University, Department of Chemistry, United Kingdom
Karl Coleman
Affiliation:
[email protected], Durham University, Department of Chemistry, United Kingdom
Dagou Zeze
Affiliation:
[email protected], Durham University, School of Engineering and Centre for Molecular and Nanoscale Electronics, United Kingdom
David Wood
Affiliation:
[email protected], Durham University, School of Engineering and Centre for Molecular and Nanoscale Electronics
Michael C Petty
Affiliation:
[email protected], Durham University, School of Engineering and Centre for Molecular and Nanoscale Electronics, United Kingdom
Get access

Abstract

Layer-by-layer films incorporating single-wall carbon nanotubes (SWNTs) with anionic or cationic coatings have been prepared. The process of self-assembly was monitored using the quartz microbalance technique, while the morphology of the resulting thin layers was studied with atomic force microscopy. A variety of different architectures have been built up. The dc conductivities of the thin films, in-plane and out-of-plane, were measured at room temperature and contrasted with reference architectures. The results show clearly that the incorporation of SWNTs into the multilayers resulted in electrically conductive thin films.

Type
Research Article
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Decher, G., Science, 277, 1232 (1997).Google Scholar
2 Multilayer Thin Films-Sequential Assembly of Nanocomposite Materials, ed. Decher, G. and Schlenoff, J.B., (Wiley-VCH, 2003).Google Scholar
3 Hammond, P.T., Advanced Materials, 16, 1271 (2004).Google Scholar
4 Shiratori, S.S. and Rubner, M.F., Macromolecules, 33, 4213 (2000).Google Scholar
5 Palumbo, M., Pearson, C., and Petty, M.C., Thin Solid Films, 483, 114 (2005).Google Scholar
6 Iijima, S., Nature, 354, 56 (1991).Google Scholar
7 Harris, P.J.F., Carbon Nanotubes and Related Structures: New Materials for the Twenty-First Century, (Cambridge University Press, 1999).Google Scholar
8 Mamedov, A.A., Kotov, N.A., Prato, M., Guldi, D.M., Wicksted, J.P., and Hirsch, A., Nature Materials, 1, 190 (2002).Google Scholar
9 Olek, M., Ostrander, J., Jurga, S., Mohwald, H., Kotov, N., Kempa, K., and Giersig, M., Nano Letters, 4, 1889 (2004).Google Scholar
10 Takahashi, T., Tsunoda, K., Yajima, H., and Ishii, T., Japanese Journal of Applied Physics Part 1-Regular Papers Short Notes & Review Papers, 43, 3636 (2004).Google Scholar
11 Geelhood, S.J., Frank, C.W., and Kanazawa, K., Journal of the Electrochemical Society, 149, H33 (2002).Google Scholar
12 Lu, C. and Lewis, O., Journal of Applied Physics, 43, 4385 (1972).Google Scholar
13 Picart, C., Lavalle, P., Hubert, P., Cuisinier, F.J.G., Decher, G., Schaaf, P., and Voegel, J.C., Langmuir, 17, 7414 (2001).Google Scholar
14 Tsukruk, V.V., Bliznyuk, V.N., Visser, D., Campbell, A.L., Bunning, T.J., and Adams, W.W., Macromolecules, 30, 6615 (1997).Google Scholar