Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-25T15:19:29.549Z Has data issue: false hasContentIssue false

Laser or Flood Exposure Generated Electrically Conducting Patterns in Polymers

Published online by Cambridge University Press:  15 February 2011

Joachim Bargon
Affiliation:
University of Bonn, Institute of Physical Chemistry, Wegelerstrasse 12, D-W-5300 BONN-1, Germany
Reinhard Baumann
Affiliation:
Institute of Technology Leipzig, Fachbereich Naturwissenschaften, P.O. Box 66, D-O-7030 Leipzig, Germany
Get access

Abstract

Electrically conducting patterns can be generated in insulating polymers or composites either via UV-flood exposure through a mask or via laser irradiation. Various lithographic concepts starting either from conventional or custom tailored polymers or from special composites have been developed and tested. Thereby electrically conducting polymers are photogenerated either directly from a self-developing photosensitive precursor or via a twocomponent redox approach using one of the components as a vapor in an otherwise dry process. The electrically conducting patterns so obtained may be reinforced by plating them with metals electrogalvanically. These processes may also be combined with laser induced ablation, whereby the intensity of the laser beam may be gated to either induce electrical conductivity of the substrate or to ablate it without rendering it conductive. Analogously, thin films of electrically conducting polymers on top of insulating polymer layers can be patterned directly using excimer laser ablation.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Gamier, F., Horowitz, G., Peng, X., Fichou, D., Adv. Mater. 2, 592 (1990)Google Scholar
2. Horowitz, G., Peng, X., Fichou, D., Gamier, F., J. Appl. Phys. 67, 528 (1990)CrossRefGoogle Scholar
3. Paloheimo, J. et al. Appl. Phys. Lett. 56, 1157 (1990)Google Scholar
4. Burroughes, J.H., Bradley, D.D.C., Brown, A.R., Marks, R.N., Friend, R.H., Burn, P.L., Holmes, A.B., Nature 347, 539 (1990)Google Scholar
5. Gupta, R., Misra, S.C.K., Malhotra, B.D., Beladakere, N.N., Appl.Phys.Lett. 58, 51 (1991)Google Scholar
6. Abdou, M.S.A., Diaz-Guijada, G.A., Aroyo, M.I., Holdcroft, S., Chem.Mater. 3, 1003 (1991)Google Scholar
7. Okano, M., Itoh, K., Fujishima, A., Honda, K., J. Electrochem. Soc. 134, 837 (1987)Google Scholar
8. Segawa, H., Shimidzu, T., Honda, K., J. Chem. Soc., Chem. Commun. 1989 132Google Scholar
9. Yoshino, K. et al. Jpn. J.Appl. Phys. 29, 1716 (1990)CrossRefGoogle Scholar
10. Bargon, J., Baumann, R., Boeker, P., SPIE, (submitted)Google Scholar
11. Novak, B.M., Hagen, E., Viswanathan, A., Magde, L., Polym. Prepr. 31, 482 (1990)Google Scholar
12. Decker, C., J. Polym. Sci., C Polym. Lett. 25, 5 (1987)Google Scholar
13. Davenas, J., Boiteux, G., Adem, E.H., Sillion, B., Synth. Met. 35, 195 (1990)Google Scholar
14. Roth, H.K., Gruber, H., Fanghänel, E., Richter, A., Hörig, W., Synth. Met. 37, 151 (1990)Google Scholar
15. Roth, H.K., Baumann, R., Schrödner, M., Gruber, H., Synth. Met. 41, 141 (1991)CrossRefGoogle Scholar
16. Baumann, R., Bargon, J., Roth, H.K., SPIE Vol.1463, 638 (1991)Google Scholar
17. Waltman, R.J., Bargon, J., Can. J. Chem. 64, 76 (1986)Google Scholar
18. De Paoli, M.A., Waltman, R.J., Diaz, A.F., Bargon, J., J. Chem. Soc, Chem. Comm. 1984, 817; J. Polym. Sci., Chem. Ed. 23, 1687 (1985)Google Scholar
19. Ueno, T., Arntz, H.D., Flesch, S., Bargon, J., J. Macromol. Sci., Chem. A25, 1557 (1988)CrossRefGoogle Scholar
20. Turro, N.J., Molecular Photochemistry, (W.A. Benjamin, New York 1965), 250 Google Scholar
21. Hatchard, C.G., Parker, C.A., Proc. Royal Soc. A235, 518 (1956)Google Scholar
22. Bargon, J., Weidenbriick, T., Ueno, T., SPIE Vol. 1262, 564 (1990)Google Scholar
23. Decker, C., Macromol. Chem., Macromol. Symp. 24, 253 (1989)Google Scholar
24. Baumann, R., Bargon, J., Roth, H.K., Mol. Cryst. & Liq. Cryst., (submitted)Google Scholar
25. Richter, A., Richter, J.M., Beye, N., Fanghänel, E., J. Prakt. Chem., 329, 811 (1987)CrossRefGoogle Scholar