Hostname: page-component-78c5997874-dh8gc Total loading time: 0 Render date: 2024-11-05T13:02:11.387Z Has data issue: false hasContentIssue false
  • English
  • Français

Kinetics of Electrochromic Effect in Amorphous Tungsten Trioxide Films

Published online by Cambridge University Press:  15 February 2011

I. A. Konovalov ,
V. B. Nechitajlo  and
E. Shushakova
I. A. Konovalov
Affiliation:
Toronto, Canada, [email protected]
V. B. Nechitajlo
Affiliation:
Institute of Physics, 46 Pr. Nauki, Kiev, Ukraine.
E. Shushakova
Affiliation:
Toronto, Canada, [email protected]
Get access

Abstract

Reversible coloration occurs in tungsten trioxide (WO3) films when double injection of electrons and ions is provided in its volume. Experiments were performed in electrochemical cell with liquid electrolyte, where protons were used for injection in amorphous WO3 films. Kinetics of electrochromic coloration process was studied in spectral range of 300 nm to 1200 nm. Dependence of optical density on injected charge was found to be different in various spectral regions for coloring and bleaching. Infrared vibrational spectra of electro-chemically colored crystalline and amorphous WO3 were obtained. Electronic structure features of amorphous WO3 related to electorchromism are discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 453: Symposium R – Solid State Chemistry of Inorganic Materials , 1996 , 665
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Deb, S., Sol. Ener. Mater. Sol. Cells, 39, 2 (1995).Google Scholar
2. Bechinger, C., Ferrere, S., Zaban, A., Sprague, J., Nature, 383, 608 (1996).Google Scholar
3. Faughnan, B., Crandall, R., Heyman, P., RCA Rev., 36, 197 (1975)Google Scholar
4. Konovalov, I., Kulyupin, Yu., Nechitajlo, V., Sukharier, A., Zhur. Tekh. Fiz., 31, 552 (1986) [Sov. Phys. Tech. Phys. 31, 431 (1986)].Google Scholar
5. Daumremont-Smith, W., Green, M., Kang, K., Electrochimia Acta, 22, 751 (1977).Google Scholar
6. Gavrilyuk, A., Prokhvatilov, B., Chudnovskii, F., Fiz, Tver. Tela, 24, 982 (1982). [Sov. Phys. Solid State, 24, 558 (1982)].Google Scholar
7. Shiyanovskaya, I., Ratajczak, H., Baran, J., Marchewka, M., J. Mol. Struc., 348, 99 (1995).Google Scholar
8. Ramans, G., Gabrusenoks, E., Veispals, A., Phys. St. Sol. A, 74, K41 (1982).Google Scholar
9. Mercier, R., Bonke, O., Bonke, C., Robert, G., Mat. Res. Bull., 18, 1, (1983).Google Scholar
10. Hashimoto, S., Matsuoka, H., J. Appl. Phys., 69, 933 (1991).Google Scholar
11. Kopp, L., Harmon, B., Liu, S., Sol. St. Com., 22, 677 (1977).Google Scholar
12. Bullet, D., J. Phys. C, 16, 2197 (1983).Google Scholar
13. Gubskii, A., Kovtun, A., Sachenko, V., Ukr. Fiz. Zh. (USSR), 28, 441 (1983), (in Russian).Google Scholar
14. Vedrinskii, R., Gubskii, A., Prosandeev, S., Sachenko, V., Izv. Akad. Nauk USSR, 46, 742 (1982), (in Russian).Google Scholar
15. Gubskii, A., Kovtun, A. (private communication).Google Scholar