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Isocyanate-Derived Organic Aerogels: Polyureas, Polyimides, Polyamides

Published online by Cambridge University Press:  28 January 2011

Nicholas Leventis ,
Chariklia Sotiriou-Leventis ,
Naveen Chandrasekaran ,
Sudhir Mulik ,
Chakkaravarthy Chidambareswarapattar ,
Anand Sadekar ,
Dhairyashil Mohite ,
Shruti S. Mahadik ,
Zachary J. Larimore  and
Hongbing Lu
...Show all authors
Nicholas Leventis
Affiliation:
Department of Chemistry, Missouri University of Science and Technology, Rolla, MO 65409, U.S.A. ([email protected])
Chariklia Sotiriou-Leventis
Affiliation:
Department of Chemistry, Missouri University of Science and Technology, Rolla, MO 65409, U.S.A. ([email protected])
Naveen Chandrasekaran
Affiliation:
Department of Chemistry, Missouri University of Science and Technology, Rolla, MO 65409, U.S.A. ([email protected])
Sudhir Mulik
Affiliation:
Department of Chemistry, Missouri University of Science and Technology, Rolla, MO 65409, U.S.A. ([email protected])
Chakkaravarthy Chidambareswarapattar
Affiliation:
Department of Chemistry, Missouri University of Science and Technology, Rolla, MO 65409, U.S.A. ([email protected])
Anand Sadekar
Affiliation:
Department of Chemistry, Missouri University of Science and Technology, Rolla, MO 65409, U.S.A. ([email protected])
Dhairyashil Mohite
Affiliation:
Department of Chemistry, Missouri University of Science and Technology, Rolla, MO 65409, U.S.A. ([email protected])
Shruti S. Mahadik
Affiliation:
Department of Chemistry, Missouri University of Science and Technology, Rolla, MO 65409, U.S.A. ([email protected])
Zachary J. Larimore
Affiliation:
Department of Chemistry, Missouri University of Science and Technology, Rolla, MO 65409, U.S.A. ([email protected])
Hongbing Lu
Affiliation:
Department of Mechanical Engineering, University of Texas at Dallas, Richardson, TX 75080, U.S.A.
Gitogo Churu
Affiliation:
Department of Mechanical Engineering, University of Texas at Dallas, Richardson, TX 75080, U.S.A.
Joseph T. Mang
Affiliation:
Los Alamos National Laboratory, Los Alamos, NM 87545, U.S.A.
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Abstract

We describe organic aerogels derived from multifunctional isocyanates through reaction with water (polyureas), acid andydrides (polyimides) and carboxylic acids (polyamides). All processes are invariably single-step, one-pot and take place at room or slightly elevated temperatures. The resulting materials are robust, their density may vary over a very wide range and their nanomorphology can be either particulate or fibrous, but in all cases they all consist of similarly sized primary particles.

Keywords

aerogelpolymernanostructure
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1306: Symposium BB – Aerogels and Aerogel-Inspired Materials , 2011 , mrsf10-1306-bb03-01
Copyright
Copyright © Materials Research Society 2011

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References

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