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IRS and ESR Characterizations of Nanocomposite Thin Films Derived From Alkanethiolates and Gold Nanoparticles

Published online by Cambridge University Press:  10 February 2011

W. X. Zheng ,
F. L. Leibowitz ,
M. M. Maye ,
D. C. Gilbert ,
D. C. Doetschman  and
C. J. Zhong
W. X. Zheng
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902
F. L. Leibowitz
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902
M. M. Maye
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902
D. C. Gilbert
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902
D. C. Doetschman
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902
C. J. Zhong
Affiliation:
Department of Chemistry, State University of New York at Binghamton, Binghamton, NY 13902, [email protected]
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Abstract

A key to the ultimate technological applications of core-shell nanoparticle materials is the understanding of the structure-property correlation. This work focuses on the characterizations of the structural properties for composite thin films derived from gold nanoparticles and thiolates using infrared reflectance spectroscopic (IRS) and electron spin resonance (ESR) techniques. IRS provides information on molecular packing and ordering of the shell components in the films, which relates to the molecular interactions and interfacial reactivities. ESR probes the conduction electron spin resonance properties of the nanosized cores, which can be correlated with the network or environmental electronic effects on the crystal cores. Results are discussed in terms of their correlation with the nanoparticle core sizes and the organic shell functionality.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 591 , 1999 , 255
Copyright
Copyright © Materials Research Society 2000

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References

REFERENCES

1.Hostetler, M. J. and Murray, R. J., Curr. Opin. Colloid Interface Sci., 2, 42 (1997)(and refes. therein.).Google Scholar
2. (a) Brust, M., Bethell, D.,Kiely, C. J. and Schiffrin, D. J., Langmuir, 14, 5425. (1998)(b) M. Brust, M. Walker, D. Bethell, D. J. Schiffrin and R. Whyman, J. Chem. Soc., Chem. Commun. 801.(1994).Google Scholar
3. (a) Hostetler, M. J., Zhong, C. J., Yen, B. K. H., Anderegg, J., Gross, S. M., Evans, N. D.,Porter, M. D. and Murray, R. W., J. Amer. Chem. Soc. 120, 9396. (1998)(b) M. J. Hostetler, J. J. Stokes, R. W. Murray, Langmuir 12, 3604 (1996).Google Scholar
4. (a) Zhong, C. J., Zheng, W. X. and Leibowitz, F. L., Electrochem. Commun., 1, 72 (1999). (b) F. L. Leibowitz, W. X. Zheng, M. M. Maye and C. J. Zhong, Anal. Chem., (in press).Google Scholar
5. (a) Zhong, C. J., Zheng, W. X., Leibowitz, F. L. and Eichelberger, H. H., Chem. Commun., 13, 1211 (1999). (b) M. M. Maye, W. X. Zheng, F. L. Leibowitz, N. K. Ly and C. J. Zhong, Langmuir, (in press).Google Scholar
6.Templeton, A. C., Hostetler, M. J., Warmoth, E. K., Chen, S. W., Hartshorn, C. M., Krishnamurthy, V. M., Forbes, M. D. E. and Murray, R. W., J. Am. Chem. Soc., 120, 4845 (1998).Google Scholar
7.Teranishi, T., Hori, H. and Miyake, M., J. Phys. Chem., 101, 5774 (1997).Google Scholar
8.Li, X. and Vannice, A., J. Catalysis, 151, 87 (1995).Google Scholar
9.Sako, S. and Ohshima, K., J. Phys. Soc, Jpn., 65, 4062 (1996).Google Scholar
10.Kimura, K. and Bandow, S., J. Colloid Interface Sci., 171, 356 (1995).Google Scholar
11.PorterT, M. D.. Bright, B., Allara, D. L. and Chidsey, C. E., J. Am. Chem. Soc. 109, 3559.(1987).Google Scholar
12.Musick, M. D., Pena, D. J., Botsko, S. L., McEvoy, T. M., Richardson, J. N. and Natan, M. J., Chem. Mater. 9, 1499 (1997).Google Scholar
13. (a) Poole, C. P., Ed., Electron Spin Resonance: A Comprehensive Treatise on Experimental Techniques, Interscience Publishers, New York, p. 814 (1967). (b) L. Walmsley, J. Mag. Resonance, 122, A 209 (1996).Google Scholar