Hostname: page-component-78c5997874-4rdpn Total loading time: 0 Render date: 2024-11-09T14:21:44.145Z Has data issue: false hasContentIssue false

Investigations on the Role of Surface Layers in HLW Glass Leaching

Published online by Cambridge University Press:  28 February 2011

R. Conradt
Affiliation:
Fraunhofer-Institut für Silicatforschung, Neunerplatz 2, D-8700 Würzburg, Federal Repuplic of Germany
H. Roggendorf
Affiliation:
Fraunhofer-Institut für Silicatforschung, Neunerplatz 2, D-8700 Würzburg, Federal Repuplic of Germany
H. Scholze
Affiliation:
Fraunhofer-Institut für Silicatforschung, Neunerplatz 2, D-8700 Würzburg, Federal Repuplic of Germany
Get access

Abstract

A corrosion test series was performed to clarify the role of reaction product layers on the corrosion of a simulated HLW borosilicate glass in a salt brine under hydrothermal conditions. The layers were unprotective at 200°C. At 120°C, slight protective effects ocurred when the leachant contained dissolved reaction products. The consequence for the long term behaviour between 120 and 200°C is a constant glass dissolution rate.

Type
Research Article
Copyright
Copyright © Materials Research Society 1985

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Literature

1. Kuhn, W.L. and Peters, R.D., in Scientific Basis for Nuclear Waste Management VI, edited by Brookins, D.G. (Elsevier Science Publishers, New York, 1983), p. 167 Google Scholar
2. Wallace, R.M. and Wicks, G.G., in Scientific Basis for Nuclear Waste Management VI, edited by Brookins, D.G. (Elsevier Science Publishers, New York, 1983), p. 23Google Scholar
3. Machiels, A.J. and Pescatore, C., in Scientific Basis for Nuclear Waste Management VI, edited by Brookins, D.G. (Elsevier Science Publishers, New York, 1983), p. 209Google Scholar
4. Chick, L.A. and Pederson, L.R., Scientific Basis for Nuclear Waste Management VI, edited by McVay, G.L. (Elsevier Science Publishers, New York, 1984), p. 635Google Scholar
5. Grambow, B. and Strachan, D.M., Scientific Basis for Nuclear Waste Management VI, edited by McVay, G.L. (Elsevier Science Publishers, New York, 1984), p. 623Google Scholar
6. Haaker, R., Malow, G., and Offermann, P., Scientific Basis for Nuclear Waste Management VI, VIII, edited by Jantzen, C.M., Stone, J.A., and Ewing, R.C. (Elsevier Science Publishers, New York, 1985), p. 121Google Scholar
7. Conradt, R., Roggendorf, H., and Scholze, H., Scientific Basis for Nuclear Waste Management VI, VIII, edited by Jantzen, C.M., Stone, J.A., and Ewing, R.C. (Elsevier Science Publishers, New York, 1985), p. 155Google Scholar
8. Conradt, R., Roggendorf, H., and Scholze, H., Scientific Basis for Nuclear Waste Management VI, VII, edited by McVay, G.L. (Elsevier Science Publishers, New York, 1984), p. 9Google Scholar
9. Scholze, H., Conradt, R., Engelke, H., and Roggendorf, H., Scientific Basis for Nuclear Waste Management VI, V, edited by Lutze, W. (Elsevier Science Publishers, New York, 1982), p. 173Google Scholar
10. Grambow, B., Scientific Basis for Nuclear Waste Management VI, VII, edited by Jantzen, C.M., Stone, J.A., and Ewing, R.C. (Elsevier Science Publishers, New York, 1985), p. 15Google Scholar
11. Lutze, W., private communicationGoogle Scholar
12. Boksay, Z., Bouquet, G., and Dobos, S., Phys. Chem. Glasses 9, 69(1968)Google Scholar