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Investigation into the Thermal and Mechanical Behavior of PMMA/Alumina Nanocomposites

Published online by Cambridge University Press:  21 March 2011

Benjamin J. Ash ,
Jason Stone ,
Diana F. Rogers ,
Linda S. Schadler ,
Richard W. Siegel ,
Brian C. Benicewicz  and
Thomas Apple
Benjamin J. Ash
Affiliation:
Department of Materials Science and Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180-3590
Jason Stone
Affiliation:
Department of Materials Science and Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180-3590
Diana F. Rogers
Affiliation:
Department of Chemistry, Rensselaer Polytechnic Institute, Troy, NY 12180-3590
Linda S. Schadler
Affiliation:
Department of Materials Science and Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180-3590
Richard W. Siegel
Affiliation:
Department of Materials Science and Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180-3590
Brian C. Benicewicz
Affiliation:
Department of Chemistry, Rensselaer Polytechnic Institute, Troy, NY 12180-3590
Thomas Apple
Affiliation:
Department of Chemistry, Rensselaer Polytechnic Institute, Troy, NY 12180-3590
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Abstract

Polymethylmethacrylate (PMMA) nanocomposites were synthesized by free radical polymerization in the presence of various weight percentages of alumina (Al2O3) nanoparticles. The resulting nanocomposites show an average increase of 600% in strain-to-failure and the appearance of a well-defined yield point. Concurrently, the glass transition temperature (Tg) of the composites decreased 20°C, while the ultimate strength and the Young's modulus decreased by 20% and 15%, respectively.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 661: Symposium KK – Filled & Nanocomposite Polymer Materials , 2000 , KK2.10
Copyright
Copyright © Materials Research Society 2001

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References

REFERENCES

1. Sumita, M., Tsukihi, H., Miyasaka, K., and Ishikawa, K., J. Appl. Polym. Sci. 29, 1523 (1984).Google Scholar
2. Ou, Y., Yang, F., and Yu, Z, J. Polym. Sci.: B 36, 789 (1998).Google Scholar
3. Cousin, P. and Smith, P., J. Polym. Sci. 32, 459 (1994).Google Scholar
4. Hergeth, W., Steinau, U., Bittrich, H., Simon, G., and Schmutzler, K., Polymer 30, 254 (1989).Google Scholar
5. Iisaka, K. and Shibayama, K., J. Appl. Polym. Sci. 22, 3135 (1978).Google Scholar
6. Becker, C., Mueller, P., and Schmidt, H., SPIE 3469, 88 (1998).Google Scholar
7. Lazzeri, A. and Bucknall, C.B. J. Mater. Sci. 28, 6799 (1993).Google Scholar
8. Wu, S., J. Appl. Polym. Sci. 35, 549 (1988).Google Scholar
9. Sternstein, S., Yielding Modes in Glassy Polymers, Polymeric Materials: Relationships Between Structure and Mechanical Behavior, ed. Baer, and Radcliffe, , (American Society for Metals, Metals Park, Ohio, 1973) pp 369–410.Google Scholar
10. Brotzman, R., U.S. Patent No. 05993967, (1999).Google Scholar
11. Balke, S.T. and Hamielec, A.E., J. Appl. Poly. Sci. 17, 905 (1973).Google Scholar
12. Annual Book of ASTM Standards, Vol 14.02, D638 – 95.Google Scholar
13. Young, R.J. and Lovell, P.A., Introduction to Polymers (Chapman and Hall, New York, New York, 1991).Google Scholar
14. Nielsen, L. and Landel, R., Mechanical Properties of Polymers and Composites, Chapter 7 (Marcel Dekker Inc., New York, 1994).Google Scholar
15. Brandrup, J., Immergut, E.H., and Grulke, E.A., ed., Polymer Handbook (John Wiley & Sons, Inc., New York, 1999).Google Scholar
16. Jiang, Q., Shi, H.X., and Li, J., Thin Solid Films 354, 283 (1999).Google Scholar
17. Forrest, J.A., , J.A., Dalnoki-Veress, K., Stevens, J.R., and Kutcher, J.R., Phys. Rev. Lett. 77, 2002 (1996).Google Scholar
18. Mattsson, J., Forrest, J.A., and Börjesson, L., Physical Rev. E, 62, 5187 (2000).Google Scholar