Hostname: page-component-586b7cd67f-dlnhk Total loading time: 0 Render date: 2024-11-29T07:59:06.844Z Has data issue: false hasContentIssue false
  • English
  • Français

Interpenetrating Organometallic Polymer Networks (IOPN's): Novel Advanced Materials

Published online by Cambridge University Press:  15 February 2011

B. Corain ,
M. Zecca ,
C. Corvaja ,
G. Palma ,
S. Lora  and
K. Jerabek
B. Corain
Affiliation:
University of Padova, Dept. Inorganic Chemistry, via Marzolo 1, and Dept. Physical Chemistry, via Loredan 2, 135131 Padova, Italy C.N.R.,Centro Studio Stabilità e Reattività Composti Coordinazione, via Marzolo 1, I35131 Padova, Italy and Institute F.R.A.E., I35020 Legnaro, Italy
M. Zecca
Affiliation:
University of Padova, Dept. Inorganic Chemistry, via Marzolo 1, and Dept. Physical Chemistry, via Loredan 2, 135131 Padova, Italy
C. Corvaja
Affiliation:
University of Padova, Dept. Inorganic Chemistry, via Marzolo 1, and Dept. Physical Chemistry, via Loredan 2, 135131 Padova, Italy
G. Palma
Affiliation:
University of Padova, Dept. Inorganic Chemistry, via Marzolo 1, and Dept. Physical Chemistry, via Loredan 2, 135131 Padova, Italy
S. Lora
Affiliation:
C.N.R.,Centro Studio Stabilità e Reattività Composti Coordinazione, via Marzolo 1, I35131 Padova, Italy and Institute F.R.A.E., I35020 Legnaro, Italy
K. Jerabek
Affiliation:
Czechoslovak Academy of Science, Institute Chemical Processes Fundamentals, 165 02 Praha 6 - Suchdol, Czechoslovakia
Get access

Abstract

A cross-linked copolymer of vinylferrocene and dimethyl-acrylamide is generated inside the less dense microporous domains of a cross-linked polydimethylacrylamide matrix. I.S.E.C. and E.S.R. data reveal that the obtained composite is in fact an I.P.N.(Interpenetrating Polymer Network) material.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 274: Symposium R – Submicron Multiphase Materials , 1992 , 103
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Foger, K. in Catalysis, edited by Anderson, J.R. and Boudart, M. (Springer Verlag, Berlin, 1984).Google Scholar
2. Bond, G.C., Chem. Soc. Rev., 12, 441 (1991).Google Scholar
3. a) Pittman, C. U. Jr. and Rausch, M. D., Pure Appl. Chem., 614 (1986). b) J.E. Sheats in Kirk-Othmer “Encyclooedia of Chemical Technology”, 3rd ed. (John Wiley & Sons, Inc., New York, 1981), vol.15, pag. 184.Google Scholar
4. a) Pearce, R. and Patterson, W.R., Catalysis and Chemical Processes (Blackie & Son Ltd., Glasgow, 1981). b) C.N. Satterfield, Heteroaeneous Catalysis in Practice (McGraw-Hill Book Company, New York, 1980).Google Scholar
5. Haag, W.O. and Whitehurst, D.D., German Patents 1800371 (1989), 1800379 (1969), 1800380 (1969).Google Scholar
6. Parshall, G.W., Homoaeneous Catalysis (Wiley-Interscience Publication, New York,1980), p. 227.Google Scholar
7. Hartley, F.R., Suoported Metal Complexes (D. Reidel, Dordrecht, 1985).Google Scholar
8. See ref 7, p. 3.Google Scholar
9. Pittmann, C.U. Jr., in Comorehensive Oraanometallic chemistry, edited by Wilkinson, G. et al. (Pergamon, Oxford, 1982) Vol.8, p. 553.Google Scholar
10. Lieto, J., Milstein, D., Albright, R. L., Minkiewicz, J. V. and Gates, B. C., Chemtech, 1983, 46.Google Scholar
11. Gates, B.C., Catalytic Chemistry, (John Wiley & Sons, Inc., New York, 1992), p. 182.Google Scholar
12. Arshady, R., Adv. Mater., 3, 182 (1991).Google Scholar
13. For a recent example see Corain, B., Basato, M.. Zecca, M., Braca, G., Galletti, A.M. Raspolli, Lora, S., Palma, G. and Guglielminotti, E., J. Mol. Catal., 73, 23 (1992).Google Scholar
14. Corain, B., Sam, F.O., Zecca, M., Veronese, A.C., Palma, G. and Lora, S., Makromol.Chem.Rapid Commun., 10, 69 (1990).Google Scholar
15. Pomogailo, A.D. and Savastyanov, V.S., IMS-REV Macromol. Chem. Phys., C25, 375 (1985).Google Scholar
16. Arshady, R., Corain, B., Lora, S., Palma, G., Russo, U., Sam, F.O. and Zecca, M., Adv. Mater., 2, 412 (1990)Google Scholar
17. Corain, B., Jerabek, K., Lora, S., Palma, G. and Zecca, M., Adv. Mater., 4, 97 (1992).Google Scholar
18. Arshady, R., Basato, M., Corain, B., Giustina, L. Della, Lora, S., Palma, G., Roncato, M. and Zecca, M., J. Mol. Catal., 53, 111 (1989) and references therein.Google Scholar
19. Sperling, L. H., Chemtech, 104 (1988).Google Scholar
20. Jerabek, K., Anal. Chem., 57, 1598 (1985).Google Scholar
21. Martini, G., Ottaviani, M. F. and Romanelli, M., J. Colloid Interface Sci., 115, 87 (1987).Google Scholar
22. Harvey, R. D. and Schlick, S., Polymer, 30, 11 (1989).Google Scholar
23. Cotton, F. A. and Wilkinson, G., Advanced Inoraanic Chemistry, 5th ed. (John Wiley & Sons, Inc., New York, 1988), p. 1173.Google Scholar
24. Various authors in Spin labelling Theory and Anolication, edited by Berliner, L.J. (Academic Press, New York, 1976).Google Scholar
25. Nimtz, G., in Correlations and Connectivity, edited by Stanley, H.E. and Ostrowsky, N. (NATO ASI Series, 118, Kluwer, Dordrecht, 1990), p. 225.Google Scholar