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Interlayer Charge Conversion Through Intercalation of Polycations into a Synthetic Swelling Mica

Published online by Cambridge University Press:  26 February 2011

Hideo Hata ,
Yoji Kobayashi  and
Thomas E Mallouk
Hideo Hata
Affiliation:
[email protected], The Pennsylvania State University, Department of Chemistry, 218 Chemistry Building, University Park, PA, 16801, United States, 814-865-5855
Yoji Kobayashi
Affiliation:
[email protected], The Pennsylvania State University, Department of Chemistry, University Park, PA, 16802, United States
Thomas E Mallouk
Affiliation:
[email protected], The Pennsylvania State University, Department of Chemistry, University Park, PA, 16802, United States
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Abstract

A layered host material with the ability to encapsulate anionic substances was synthesized by intercalating polycations into a synthetic fluoromica. A cationic polyelectrolyte coiled in the interlayer galleries to overcompensate the negative charge on the silicate sheets, and bulky anionic dye molecules could site-selectively be intercalated into interlayer in which the polyelectorlyte coiled.

Keywords

adsorptionlayeredpolymer
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 988: Symposium QQ – Solid-State Chemistry of Inorganic Materials VI , 2006 , 0988-QQ03-03
Copyright
Copyright © Materials Research Society 2007

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References

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