Hostname: page-component-586b7cd67f-rdxmf Total loading time: 0 Render date: 2024-11-29T08:18:17.057Z Has data issue: false hasContentIssue false
  • English
  • Français

Interfacial Structure of Electrically Conducting Adsorbed Multilayers

Published online by Cambridge University Press:  15 February 2011

G. J. Kellogg ,
A.M. Mayes ,
W. B. Stockton ,
M. Ferreira ,
M.F. Rubner  and
S.K. Satija
G. J. Kellogg
Affiliation:
Department of Materials Science and Engineering, M.I.T., Cambridge, MA 02139
A.M. Mayes
Affiliation:
Department of Materials Science and Engineering, M.I.T., Cambridge, MA 02139
W. B. Stockton
Affiliation:
Department of Materials Science and Engineering, M.I.T., Cambridge, MA 02139
M. Ferreira
Affiliation:
Department of Materials Science and Engineering, M.I.T., Cambridge, MA 02139
M.F. Rubner
Affiliation:
Department of Materials Science and Engineering, M.I.T., Cambridge, MA 02139
S.K. Satija
Affiliation:
Reactor Radiation Division, Natl. Institute of Standards and Technology, Gaithersburg, MD 20899
Get access

Abstract

The multilayer organization of sulfonated polyaniline/polyallylamine (SPAN/PAH) films was investigated by neutron reflectivity. Films were prepared by sequential adsorption of polycations and polyanions from dilute solution. Scattering contrast was achieved by selective deuteration of blocks of bilayers at varying intervals along the films. The internal organization of the multilayer structure was found to decay significantly with increasing number of bilayer depositions. In addition, a high degree of roughness was determined at the free surfaces of the films. Together, these results suggest that both conformal and nonconformal roughness are present in the films, i.e., defects introduced during individual layer depositions are to some degree transferred to the surface of subsequently deposited layers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 351: Symposium V – Molecularly Designed Ultrafine/Nanostructured Materials , 1994 , 325
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Decher, G., Hong, J.D. and Schmitt, J., Thin Solid Films 210, 831 (1992).Google Scholar
2. Ferreira, M., Cheung, J.H., Scruggs, W. and Rubner, M.F., “Molecular self-assembly of conducting polymers: a new process for fabricating electrically conducting thin films”, SPE Proc., New Orleans, LA 1993.Google Scholar
3. Ferreira, M., Cheung, J.H. and Rubner, M.F., “Molecular self-assembly of conjugated polyions: a new process for fabricating multilayer thin film heterostructures”, Thin Solid Films (in press).Google Scholar
4. Anastasiadis, S.H., Russell, T.P., Satija, S.K. and Majkrzak, C.F., J. Chem. Phys. 92, 5677 (1990).Google Scholar
5. Mayes, A.M., Russell, T.P., Satija, S.K. and Majkrzak, C.F., Macromolecules 25, 6523 (1992).Google Scholar
6. Schmitt, J., Grunewald, T., Decher, G., Pershan, P.S., Kjaer, K., and Losche, M., Macromolecules 26, 7058 (1993).Google Scholar