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Interfacial Reactions Between Titanium and Borate Glass

Published online by Cambridge University Press:  15 February 2011

R. K. Brow
Affiliation:
Sandia National Labs, Dept. 1845, Albuquerque, NM 87185
S. K. Saha
Affiliation:
Lehigh University, Dept. of Materials Science, Bethlehem, PA 18015
J. I. Goldstein
Affiliation:
Lehigh University, Dept. of Materials Science, Bethlehem, PA 18015
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Abstract

Interfacial reactions between the melts of several borate glasses and titanium have been investigated by analytical scanning electron microscopy (ASEM) and by x-ray photoelectron spectroscopy (XPS). A thin titanium boride interfacial layer is detected by XPS after short (30 minutes) thermal treatments. ASEM analyses after longer thermal treatments (8–120 hours) reveal boron-rich interfacial layers and boride precipitates in the Ti side of the interface.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

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References

1. Passerone, A., Valbusa, G., Biagini, E., J. Mater. Sci. 12 (12), 2465 (1977).CrossRefGoogle Scholar
2. Feipeng, Z., Tomsia, A.P., Pask, J.A., Proc. 33rd Pacific Coast Meeting Amer. Ceram. Soc., San Francisco, CA, 1980 pp. 76–78.Google Scholar
3. Brow, R. K. and Watkins, R. D., in Technology of Glass, Ceramic, or Glass-Ceramic to Metal Sealing, edited by Moddeman, W. E., et al. (Winter Annual Meeting, Amer. Soc. Mech. Eng., Boston, MA, 1987) pp. 2530.Google Scholar
4. West, J.K., Clark, A.E., Hall, M.B., Turner, G.E., in Handbook of Bioactive Ceramics, Vol.1, edited by Yamamuro, T., et al. (CRC Press, Boca Raton, FL, 1990) pp. 161166.Google Scholar
5. Brow, R.K. and Watkins, R.D., U.S. Patent No. 5,104,738 (14 April 1992).Google Scholar
6. Chopra, D.R., Chourasia, A.R., Dillinger, T.R., Peterson, K.L., Gnade, B., J. Vac. Sci. Technol. A, 5(4), 1984 (1987).Google Scholar
7. Hautaniemi, J.A., Hero, H., Juhanoja, J.T., J. Mater. Sci. Mater. Med., 3, 186 (1992).Google Scholar
8. Chaug, Y.S., Chou, N.J., Kim, Y.H., J. Vac. Sci Technol. A, 5(4) 1288 (1987).CrossRefGoogle Scholar
9. Mavel, G., Escard, J., Costa, P., Castaing, J., Surf. Sci., 35, 109 (1973).Google Scholar
10. Eriksson, G., Chemica Scripta, 8 100 (1975).Google Scholar
11. Stull, D. R., Propet, H., et al. JANAF Thermochemical Tables, 2 nd Ed., (US Dept. of Commerce, National Bureau of Standards, Washington, DC, 1970).CrossRefGoogle Scholar
12. Murray, J. L., Liao, P. K., Spear, K. E., Bull. Alloy Phase Diagrams, 7(6) 550 (1986).Google Scholar