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In-Situ Raman Spectroscopy Studies of Room-Temperature and Hydrothermal Reactions

Published online by Cambridge University Press:  13 June 2012

Brendan T. McGrail ,
Laurent J. Jouffret ,
Eric M. Villa  and
Peter C. Burns
Brendan T. McGrail
Affiliation:
Department of Civil Engineering and Geological Sciences, University of Notre Dame, Notre Dame, IN, 46556, USA
Laurent J. Jouffret
Affiliation:
Department of Civil Engineering and Geological Sciences, University of Notre Dame, Notre Dame, IN, 46556, USA
Eric M. Villa
Affiliation:
Department of Civil Engineering and Geological Sciences, University of Notre Dame, Notre Dame, IN, 46556, USA
Peter C. Burns
Affiliation:
Department of Civil Engineering and Geological Sciences, University of Notre Dame, Notre Dame, IN, 46556, USA
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Abstract

By contracting with the Parr Instrument Company and Bruker Optical Systems, we have developed a system for continuous monitoring of hydrothermal and room temperature reactions by Raman spectroscopy. Using the uranyl peroxide cage cluster {[UO2(O2)(OH)]16[UO2(OM)2]4}24- (denoted {U20R}) and a coordination polymer made from uranyl ions and 4,4’-biphenyldicarboxylate as model systems, we demonstrate the spectroscopically observable changes associated with reaction progress and crystallization.

Keywords

actinidehydrothermalRaman spectroscopy
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1444: Symposium S/Y – Actinides and Nuclear Energy Materials , 2012 , mrss12-1444-y06-11
Copyright
Copyright © Materials Research Society 2012

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References

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