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In-Situ Corrosion Studies on Cast Steel for a High-Level Waste Packaging in a Rock Salt Repository

Published online by Cambridge University Press:  26 February 2011

W. Schwarzkopf ,
E. Smailos  and
R. Koster
W. Schwarzkopf
Affiliation:
Kernforschungszentrum Karlsruhe GmbH, Postfach 3640, D-7500 Karlsruhe 1, Federal Republic of Germany
E. Smailos
Affiliation:
Kernforschungszentrum Karlsruhe GmbH, Postfach 3640, D-7500 Karlsruhe 1, Federal Republic of Germany
R. Koster
Affiliation:
Kernforschungszentrum Karlsruhe GmbH, Postfach 3640, D-7500 Karlsruhe 1, Federal Republic of Germany
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Abstract

Previous corrosion studies performed on a number of materials have shown that unalloyed steels are promising materials for long-term resistant packagings to be used in disposal of heat-generating wastes in rock salt formations. This is the reason why those steels are the subject of more detailed investigations. This paper reports an in-situ experiment conducted in the Asse salt mine in which the influence of selected characteristics (welding, shape) of containers on the corrosion behaviour of cast steel was studied. The material was tested in NaCl brine which might intrude into an HLW borehole in an accident scenario. For this, an electron beam welded cast-steel tube was stored for 18 months in a 2-m deep heated borehole and the annular gap between the tube and the borehole wall was filled with saturated NaCl brine. The vertical temperature profile in the borehole was in the range from 90°C to 200°C; the maximum temperature occurred in the center of the heated zone and the minimum temperature in the upper parts of tube.

Under the testing conditions cast steel was subjected to general corrosion at a maximum corrosion rate of 120 μm/a. Considering this magnitude of the corrosion rates, the resulting corrosion allowances are technically acceptable for a packaging having long service-lives. Pitting and crevice corrosion as well as stress-corrosion cracking did not occur in cast steel, and electron beam welding did not exert a noticeable influence on cast-steel corrosion. With these results available, cast steel continues to be considered as a promising HLW packaging material.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 127: Symposium BERLIN – Scientific Basis for Nuclear Waste Management XII , 1988 , 411
Copyright
Copyright © Materials Research Society 1989

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References

REFERENCES

1. Sicherheitskriterien für die Endlagerung radioaktiver Abfälle in einem Bergwerk, Bundesanzeiger 35, No. 2, p. 45 (1983).Google Scholar
2. Smailos, E., Schwarzkopf, W., Köster, R., “Corrosion behaviour of container materials for the disposal of high-level wastes in rock salt formations,” Nuclear Science and Technology, CEC-Report, EUR 10400 (1986).Google Scholar
3. Standard practice for preparing, cleaning, and evaluating corrosion test specimens. Designation G1–81. Annual Book of ASTM Standards (1984), Vol. 03.02, pp. 87–92.Google Scholar
4. Westerman, R.E., Haberman, J.H. et al., “Corrosion and Environmental-Mechanical Characterization of Iron-Base Nuclear Waste Package Structural Barrier Materials,” PNL-5426 (1986).Google Scholar
5. Smailos, E., Köster, R., Fiehn, B., “Corrosion Behaviour of Unalloyed Steels in Solid Rock Salt/Salt Brine Environment,” in Reed, D.L., Mallinson, L.G. (eds.), Characterization of Radioactive Waste Forms, Vol. 2: Corrosion of Container Materials, pp. 156–170, EUR 11354 EN (1987).Google Scholar
6. Schwarzkopf, W., Smailos, E., Köster, R., “In-situ Corrosion Studies on Selected High-Level Waste Packaging Materials under Simulated Disposal Conditions in Rock Salt Formations,” KfK Report 4324 (1988).CrossRefGoogle Scholar
7. Schwarzkopf, W., Smailos, E., Köster, R., to be published.Google Scholar