Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-25T15:23:31.817Z Has data issue: false hasContentIssue false
  • English
  • Français

Influence of the lead-compound on PZT 30/70 thin film orientation

Published online by Cambridge University Press:  26 February 2011

Mira Mandeljc ,
Barbara Malič ,
Marija Kosec  and
Goran Dražič
Mira Mandeljc
Affiliation:
[email protected], Jožef Stefan Institute, Electronic Ceramic Department, Jamova 39, Ljubljana, N/A, 1000-Ljubljana, Slovenia, 00386 1 477 3678, 00386 1 477 3887
Barbara Malič
Affiliation:
[email protected], Jožef Stefan Institute, Slovenia
Marija Kosec
Affiliation:
[email protected], Jožef Stefan Institute, Slovenia
Goran Dražič
Affiliation:
[email protected], Jožef Stefan Institute, Slovenia
Get access

Abstract

Ferroelectric thin films based on Pb(Zr0.30Ti0.70)O3 (PZT 30/70) were prepared by Chemical Solution Deposition from lead oxide or lead acetate and transition metal alkoxides in 2-methoxyethanol at 400 °C. The choice of the lead-compound determines the composition of the PZT-sols and as a consequence the course of the thermal decomposition. In the case of PbO the local atmosphere within the bulk of the film during heating is more reducing, i.e. the partial pressure of oxygen is lower, than in the case of Pb(OAc)2 based film. Thus, in the former case a continuous layer of Pt-Pb phase is formed at 400 °C, while in Pb(OAc)2 based film only a low amount of Pt-Pb inclusions could be determined by TEM.

Keywords

solution depositionfilmnucleation & growth
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 902: Symposium T – Ferroelectric Thin Films XIII , 2005 , 0902-T03-37
Copyright
Copyright © Materials Research Society 2006

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Haertling, G.H., J. Am. Ceram. Soc., 82 (1999), 797–818.Google Scholar
2 Malič, B., Cilenšek, J., Mandeljc, M., Kosec, M., Acta Chim. Slov., 52 (2005), 259–263.Google Scholar
3 Mandeljc, M., PhD Thesis in progress.Google Scholar
4 Merkle, R., Bertagnolli, H., Ber. Bunsen Ges. Phys. Chem., 102 (1998), 1023–1031.Google Scholar
5 Kwok, C.K., Desu, S.B., J. Mater. Res., 8 (1993), 339–344.Google Scholar
6 Kosec, M., Malič, B., Mandeljc, M., Mater. Sci. Semicond. Process., 5 (2003), 97–103.Google Scholar
7 Kim, S.H., Kim, D.J., Woo, H.J., Lee, D.S., Ha, J., Hwang, C.S., Shim, I.B., Kingon, A. I., Thin Solid Films, 416 (2002), 264–270.Google Scholar
8 Aoki, K., Fakuda, Y., Numata, K., Nishimura, A., Jpn. J. Appl. Phys., 33 (1994), 5155–5158.Google Scholar
9 Chen, S.Y., Chen, I.W., Jpn. J. Appl. Phys., 36 (1997), 4451–4458.Google Scholar
10 Mandeljc, M., Malič, B., Kosec, M., MIDEM'02 Proc., Amon, S., Trontelj, L., Sorli, I., (Eds.), (MIDEM, 2002), 125–130.Google Scholar
11 Tani, T., Xu, Z., Payne, D. A., Mater. Res. Soc. Symp. Proc., 310: Ferroelectrics Thin Films III, Myers, E.R., Tuttle, B., Desu, S.B., Larsen, P.K. (Eds), MRS, Pittsburgh, (1993), 269–274.Google Scholar
12 Willems, G.J., Wouters, D.J., Maes, H.E., Integrated Ferroelectrics, 15 (1997), 19–28.Google Scholar
13 Hiboux, S., Muralt, P., J. Europ. Ceram Soc., 24 (2004), 1593–1596.Google Scholar
14 Chen, S.Y., Chen, I.W., J. Am. Ceram Soc., 77 (1994), 2332–2336.Google Scholar
15 Huang, Z., Zhang, Q., Whatmore, R.W., J. Mater. Res., 17 (1998), 1157–1159.Google Scholar
16 Huang, Z., Zhang, Q., and Whatmore, R.W., J. Appl. Phys., 86 (1999), 1662–1669.Google Scholar
17 Impey, S.A., Huang, Z., Patel, A., Beanland, R., Shorrocks, N.M., Watton, R., Whatmore, R.W., J. Appl. Phys., 83 (1998), 2202–2208.Google Scholar
18 Gong, W., Li, J.F., Chu, X., Gui, Z., Li, L., Acta Materialia, 52 (2004), 2787–2793.Google Scholar
19 Goto, S., Fujimura, N., Nishihara, T., Ito, T., J. Crystal Growth, 115 (1991), 816–820.Google Scholar
20 Kosec, M., Malič, B., Holc, J., Hrovat, M., Mandeljc, M., Benčan, A., Samardžija, Z., Dražič, G., Acta Chim. Slov., 48 (2001), 51–62.Google Scholar
21 Bradley, D.C., Mehrotra, R.C., Gaur, D.P., Metal Alkoxides, Academic press, London, 1978.Google Scholar
22 Coffman, P.R., Barlingay, C.K., Gupta, A., Dey, S.K., J. Sol-Gel Sci. Tech., 6 (1996), 83–106.Google Scholar