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Influence of Macrocyclic Ligands on Ion Transport in Solid Polyelectrolytes

Published online by Cambridge University Press:  28 February 2011

K. Chen ,
K. Doan ,
S. Ganapathiappan ,
M. Ratner  and
D. F. Shriver
K. Chen
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
K. Doan
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
S. Ganapathiappan
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
M. Ratner
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
D. F. Shriver
Affiliation:
Northwestern University, Department of Chemistry and Materials Research Center, Evanston, IL 60208
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Abstract

Cryptands and crown ethers increase the cation transport in phosphazene and alkoxyaluminate polyelectrolytes. Vibrational spectroscopy indicates that the increased conductivity originates from reduced ion pairing.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 210: Symposium L – Solid State Ionics II , 1990 , 211
Copyright
Copyright © Materials Research Society 1991

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References

1. Polymer Electrolyte Reviews; MacCallum, J. R., Vincent, C. A., Eds.; Elsevier: New York (1987).Google Scholar
2. Ratner, M. A. and Shriver, D. F., Chem. Rev. 88, 109 (1988).CrossRefGoogle Scholar
3. MacCallum, J. R., Tomlin, A. S. and Vincent, C. A., Eur. Poly. J. 22, 787 (1986).CrossRefGoogle Scholar
4. Doan, K. E., Ganapathiappan, S., Chen, K., Ratner, M. A. and Shriver, D. F., Mater. Res. Soc. Symp. Proc. 135, 343 (1989).CrossRefGoogle Scholar
5. Liu, H., Okamoto, Y., Skotheim, T., Pak, Y. S., Greenbaum, S. G., Adamic, K. J., Ibid 337.Google Scholar
6. Chen, K., Ganapathiappan, S. and Shriver, D. F., Chem. Mater. 1, 483 (1984).CrossRefGoogle Scholar
7. Doan, K. E., Heyen, B. J., Ratner, M. A. and Shriver, D. F., Chem, Mater. 2, 539 (1990).CrossRefGoogle Scholar
8. Due to the fluorescent nature of polyphosphazene sulfonates, we were not able to obtain Raman data of the polyelectrolytes.Google Scholar
9. Truter, M. R., Struct. Bonding 16 71, (1973).CrossRefGoogle Scholar