Hostname: page-component-586b7cd67f-tf8b9 Total loading time: 0 Render date: 2024-11-25T15:30:51.468Z Has data issue: false hasContentIssue false
  • English
  • Français

The Influence of Alkali Metal Hydroxides on Silica Condensation Rates: The Role of Ion Pairing

Published online by Cambridge University Press:  25 February 2011

A. V. McCormick ,
A. T. Bell  and
C. J. Radke
A. V. McCormick
Affiliation:
Department of Chemical Engineering, University of California, Berkeley, CA. 94720
A. T. Bell
Affiliation:
Department of Chemical Engineering, University of California, Berkeley, CA. 94720
C. J. Radke
Affiliation:
Department of Chemical Engineering, University of California, Berkeley, CA. 94720
Get access

Abstract

The condensation kinetics and the role of Ion pairing are investigated for silicate anions in alkaline solutions. Selective, and non-selective inversion recovery experiments are performed using the Si NMR spectrum of alkali metal silicate solutions. In this way the rates of condensation of silicate monomers is studied as a function of the nature of the base. These rates exhibit maxima with increasing cation size. The maxima are interpreted in terms of the concentration and activity of ion pair intermediates of the Si exchange reaction.

Interactions between alkali metal cations and larger silicate anions in silicate solutions are investigated using NMR spectroscopy of the cations. The chemical shift and the resonance llnewidths are used to estimate the concentration of cation-silicate ion pairs. The concentration of pairs involving large anions increases with increasing cation size. Thus it is expected that condensation kinetics are influenced by the size of the silicate fragment.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 121: Symposium H – Better Ceramics Through Chemistry III , 1988 , 67
Copyright
Copyright © Materials Research Society 1988

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Klein, L. C., Ann. Rev. Mat. Sci., 15 227 (1985).CrossRefGoogle Scholar
2. Keefer, K. D., in “Better Ceramics Through Chemistry,” MRS Symp. Proc, vol. 32, Elsevier (1984), p.15.Google Scholar
3. Her, R. K., “The Chemistry of Silica,” Wiley, New York, 1979.Google Scholar
4. Zelinski, B. J. J., and Uhlmann, D. R., J. Phys. Chem. Solids, 45(10) 1069.Google Scholar
5. Klein, L. C., and Garvey, G. J., in “Better Ceramics Through Chemistry,” MRS Symp. Proc, vol. 32, Elsevier (1984), p.33.Google Scholar
6. Falcone, J. S. Jr, in “Soluble Silicates” (Falcone, J. S. Jr, ed.), ACS Symp. Ser. 194, ACS (1982), p.133.CrossRefGoogle Scholar
7. Kelts, L. W., Effinger, N. J., and Melpolder, S. M., J. Noncryst. Solids, p.353 (1986).CrossRefGoogle Scholar
8. Barrer, R. M., “Hydrothermal Chemistry of Zeolites,” Acad. Press, London, 1982.Google Scholar
9. Fukushima, E., and Roeder, S. B. W., “Experimental Pulse NMR,” Addison-Wesley, Reading, MA, 1981.Google Scholar
10. McCormick, A. V., Bell, A. T., and Radke, C. J., to be published.Google Scholar
11. McCormick, A. V., Bell, A. T., and Radke, C. J., Zeolites 7, 193 (1987).Google Scholar
12. Bockris, J. O'M, and Reddy, A. K. N., “Modern Electrochemistry,” Plenum, New York, 1970.Google Scholar
13. Deverell, C., in “Progress in NMR Specttoscopy” (Emsley, J. W., Feeney, J., and Sutcliffe, L. H., eds.), vol 4, Pergamon, Oxford, 1969, p. 235.Google Scholar
14. McCormick, A. V., Bell, A. T., and Radke, C. J., to be published.Google Scholar
15. Lindman, B., and Forsen, S., in “NMR and the Periodic Table” (Harris, R. K. and Mann, B. E., eds.), Acad. Press, London, 1977, p.129.Google Scholar