Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-29T10:36:19.927Z Has data issue: false hasContentIssue false
  • English
  • Français

In Situ Investigation of Working Battery Electrodes Using Synchrotron X-Ray Diffraction

Published online by Cambridge University Press:  10 February 2011

N. M. Jisrawi ,
T. R. Thurston ,
X. Q. Yang ,
S. Mukerjee ,
J. McBreen ,
M. L. Daroux  and
X. K. Xing
N. M. Jisrawi
Affiliation:
Dept. of Physics, Birzeit University, P.O. Box 14, West Bank.
T. R. Thurston
Affiliation:
Dept. of Physics, Brookhaven National Laboratory, Upton, NY 11973, USA.
X. Q. Yang
Affiliation:
Dept. of Applied Science, Brookhaven National Laboratory, Upton, NY 11973, USA.
S. Mukerjee
Affiliation:
Dept. of Physics, Birzeit University, P.O. Box 14, West Bank.
J. McBreen
Affiliation:
Dept. of Applied Science, Brookhaven National Laboratory, Upton, NY 11973, USA.
M. L. Daroux
Affiliation:
Gould Electronics, Eastlake, OH 44095, USA.
X. K. Xing
Affiliation:
Gould Electronics, Eastlake, OH 44095, USA.
Get access

Abstract

The results of an in situ investigation of the structural changes that occur during the operation of working battery electrodes using synchrotron radiation are presented. Two types of electrodes were investigated: an AB2-type Laves phase alloy anode with the composition ZrxTi1-xM2 and a proprietary cell based on a LixMn2O4 spinel compound cathode made by Gould electronics. For the Laves phase alloy compositions with x=0.25 and 0.5 and M=V0.5N1.1Mn0.2Fe0.2 were examined. Cells made from two different batches of LixMn2O4 material were investigated. The relationships between battery performance and structural changes will be discussed. In the later case, we also discuss the role of over-discharging on the LixMn2O4 structure and on battery operation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 451: Symposium P – Electrochemical Synthesis and Modification , 1996 , 301
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Tarascon, J.M., Wang, E., Shokoohi, F. K., McKinnon, W.R., and Colson, S., J. Electrochem. Soc. 138, 2859(1991);Google Scholar
Tarascon, J. M. and Guyomard, D., J. Electrochem. Soc. 2864(1991).Google Scholar
2. Thackery, M. M., de Kock, A., and David, W.I., Mat. Res. Bull., 28, 1041–1049(1993).Google Scholar
3. Huot, J., Akiba, E., Ogura, T., and Ishido, Y., J. Alloys and Compounds, 218, 101–109(1995).Google Scholar
4. Hunter, J.C., J. Solid State Chem., 39, 142(1981).Google Scholar
5. Ohzuku, T., Kitagawa, M., and Hirai, T.,, J. Electrochem. Soc. 137, 769(1990).Google Scholar
6. Thurston, T.R., Jisrawi, N.M., Mukerjee, S., Yang, X.Q., McBreen, J., Daraoux, M.L., and Xing, X.K., Appl. Phys. Lett., 69, 194(1996).Google Scholar
7. Suortti, P., Thomlinson, W., Chapman, D., Gmur, N., Siddons, D.P., and Schulze, C., Nucl. Instrum. Methods A, 336, 304(1993).Google Scholar
8. Mukerjee, S., McBreen, J., Reilly, J.J., Johnson, J.R., Adzik, G., Petrov, K., Kumar, M.P.S., Zhang, W., and Srinivasan, S.,, J. Electrochem. Soc. 142, 2278(1995).Google Scholar
9. Jisrawi, N. M., Yang, X.Q., Mukerjee, S., Thurston, T.R., McBreen, J., Daraoux, M.L., and Xing, X.K., submitted to J. Electrochem. Soc.Google Scholar