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Improved hydrogen storage kinetics of nanoconfined LiBH4-MgH2 reactive hydride composites catalyzed with nickel Nanoparticles

Published online by Cambridge University Press:  15 June 2012

Thomas K. Nielsen ,
Marek Polanski ,
Bjarne R. S. Hansen ,
Søren Tolborg ,
Dorthe B. Ravnsbæk ,
Flemming Besenbacher ,
Jerzy Bystrzycki ,
Jørgen Skibsted  and
Torben R. Jensen
Thomas K. Nielsen
Affiliation:
Center for Energy Materials, Interdisciplinary Nanoscience Center (iNANO), and Department of Chemistry, Aarhus University, DK-8000 Aarhus, Denmark
Marek Polanski
Affiliation:
Faculty of Advanced Technology and Chemistry, Military University of Technology, 2 Kaliskiego Str., 00-908 Warsaw, Poland
Bjarne R. S. Hansen
Affiliation:
Center for Energy Materials, Interdisciplinary Nanoscience Center (iNANO), and Department of Chemistry, Aarhus University, DK-8000 Aarhus, Denmark
Søren Tolborg
Affiliation:
Center for Energy Materials, Interdisciplinary Nanoscience Center (iNANO), and Department of Chemistry, Aarhus University, DK-8000 Aarhus, Denmark
Dorthe B. Ravnsbæk*
Affiliation:
Center for Energy Materials, Interdisciplinary Nanoscience Center (iNANO), and Department of Chemistry, Aarhus University, DK-8000 Aarhus, Denmark
Flemming Besenbacher
Affiliation:
Interdisciplinary Nanoscience Center (iNANO) and Department of Physics and Astronomy, Aarhus University, DK-8000 Aarhus C, Denmark
Jerzy Bystrzycki
Affiliation:
Faculty of Advanced Technology and Chemistry, Military University of Technology, 2 Kaliskiego Str., 00-908 Warsaw, Poland
Jørgen Skibsted
Affiliation:
Instrument Centre for Solid-State NMR Spectroscopy, Department of Chemistry, and Interdisciplinary Nanoscience Center (iNANO), Aarhus University, DK-8000 Aarhus C, Denmark
Torben R. Jensen
Affiliation:
Center for Energy Materials, Interdisciplinary Nanoscience Center (iNANO), and Department of Chemistry, Aarhus University, DK-8000 Aarhus, Denmark
*
*Email: [email protected]
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Abstract

LiBH4 and MgH2 both have high gravimetric and volumetric hydrogen storage densities. Unfortunately, their commercial application is prevented by high thermal stability and unfavorable thermodynamic properties. Combining the two hydrides leads to a new decomposition pathway with suitable enthalpy of reaction. However, the kinetics for hydrogen release remains an obstacle but can be improved by nanoconfinement in nano porous carbon materials. Here we report on nanoconfinement of 2LiBH4-MgH2 in Ni functionalized carbon aerogels. 11B MAS NMR reveals that the nanoconfined hydrides react reversibly with hydrogen whereas simultaneous differential scanning calorimetry and mass spectroscopy clearly show that nanoconfinement facilitates lower hydrogen release temperatures than ball milling. Furthermore, Ni functionalization of the nanoporous aerogel leads to even lower hydrogen release temperatures from nanoconfined 2LiBH4-MgH2.

Keywords

energy storagecompositecatalytic
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1441: Symposium P – Advanced Materials and Nanoframeworks for Hydrogen Storage and Carbon Capture , 2012 , mrss12-1441-p06-12
Copyright
Copyright © Materials Research Society 2012

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