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Hydrothermal Synthesis of Novel Vanadium Oxides

Published online by Cambridge University Press:  15 February 2011

M. Stanley Whittingham
Affiliation:
Chemistry Department and Materials Research Center, State University of New York at Binghamton, Binghamton, NY 13902–6000, USA
Elizabeth Boylan
Affiliation:
Chemistry Department and Materials Research Center, State University of New York at Binghamton, Binghamton, NY 13902–6000, USA
Rongji Chen
Affiliation:
Chemistry Department and Materials Research Center, State University of New York at Binghamton, Binghamton, NY 13902–6000, USA
Thomas Chirayil
Affiliation:
Chemistry Department and Materials Research Center, State University of New York at Binghamton, Binghamton, NY 13902–6000, USA
Fan Zhang
Affiliation:
Chemistry Department and Materials Research Center, State University of New York at Binghamton, Binghamton, NY 13902–6000, USA
Peter Y. Zavalij
Affiliation:
Chemistry Department and Materials Research Center, State University of New York at Binghamton, Binghamton, NY 13902–6000, USA
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Abstract

Extending our prior work on tungsten and molybdenum oxides, we have found that a wide variety of vanadium oxides can be prepared using hydrothermal methods. These include a number of layer compounds as well as cluster complexes. The starting reaction medium usually contained vanadium pentoxide, an alkali containing compound such as LiOH, an organic template such as tetramethylammonium, and the pH of the whole was controlled by the addition of acid. Reaction temperature was 150°C to 200°C, and time was up to 3 days. A new lithium vanadium oxide, which has the simplest structure of any layered vanadium oxide, was formed. The lithium could be readily removed leading to a new form of vanadium dioxide. This vanadium oxide was also capable of intercalating a variety of other ionic and molecular species. Several other new vanadium oxides containing the TMA cation were also formed; one of these TMAV3O7 readily absorbed oxygen to form TMAV3O8. Addition of zinc or iron to the reaction medium caused the formation of layer structures containing double V2O5 layers; for iron the TMA was retained in the structure whereas for zinc the TMA was excluded. Changing the organic entity resulted in other new structures, for example methylamine and dimethylamine gave tetragonal structures.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1. Rouxel, J., Tournoux, M., and Bree, R., ed. Soft Chemistry Routes to New Materials -Chimie Douce-. Materials Science Forum, Vol. 152–153. 1994, Trans Tech Publications: Switzerland. Google Scholar
2. Whittingham, M. S., Current Opinion in Solid State and Materials Science, 1 (1996) 227.Google Scholar
3. Günter, J. R., Amberg, M., and Schmalle, H., Mat. Res. Bull., 24 (1989) 289.Google Scholar
4. Reis, K. P., Ramanan, A., and Whittingham, M. S., Chem. Mater., 2 (1990) 219.Google Scholar
5. Reis, K. P. and Whittingham, M. S., J. Solid State Chem., 91 (1991) 394.Google Scholar
6. Reis, K. P., Ramanan, A., Gloffke, W., and Whittingham, M. S.. Synthesis, Diffusion and Ion-Exchange in Open Structure Sodium Tungstates and YBaCuTungstates. in Solid State Ionics II. 210 (1991) 473. Boston, MA: Materials Research Society. Google Scholar
7. Reis, K. P., Ramanan, A., and Whittingham, M. S., J. Solid State Chem., 96 (1992) 31.Google Scholar
8. Reis, K. P., Prince, E., and Whittingham, M. S., Chem. Mater., 4 (1992) 307.Google Scholar
9. Zavalij, P., Guo, J., Whittingham, M. S., Jacobson, R. A., Pecharsky, V., Bucher, C., and Hwu, S.-J., J. Solid State Chem., 123 (1996) 83.Google Scholar
10. Guo, J., Zavalij, P., and Whittingham, M. S., Eur. J. Solid State Chem, 31 (1994) 833.Google Scholar
11. Guo, J.-D., Zavalij, P., and Whittingham, M. S., J. Solid State Chem, 117 (1995) 323.Google Scholar
12. Guo, J., Zavalij, P., and Whittingham, M. S., Chem. Mater., 6 (1994) 357.Google Scholar
13. Whittingham, M. S., Li, J., Guo, J., and Zavalij, P.. Hydrothermal Synthesis of New Oxide Materials using the Tetramethyl Ammonium Ion. in Soft Chemistry Routes to New Materials. 152–153 (1993) 99. Nantes, France: Trans Tech Publications Ltd. Google Scholar
14. Li, Y. J. and Whittingham, M. S., Solid State Ionics, 63 (1993) 391.Google Scholar
15. Whittingham, M. S., Guo, J., Chen, R., Chirayil, T., Janauer, G., and Zavalij, P., Solid State Ionics, 75 (1995) 257.Google Scholar
16. Zavalij, P., Whittingham, M. S., Boylan, E. A., Pecharsky, V. K., and Jacobson, R. A., Z. Kryst, 211 (1996) 464.Google Scholar
17. Chirayil, T., Zavalij, P., and Whittingham, M. S., Solid State Ionics, 84 (1996) 163.Google Scholar
18. Chirayil, T., Zavalij, P., and Whittingham, M. S., J. Electrochem. Soc, 143 (1996) L193. Google Scholar
19. Chirayil, T. A., Zavalij, P. Y., and Whittingham, M. S., Chem. Commun., (1996) in press.Google Scholar
20. Nazar, L. F., Personal Communication, (1996)Google Scholar
21. Boylan, E. A., Chirayil, T., Hinz, J., Zavalij, P., and Whittingham, M. S., Solid State Ionics, 90 (1996)1.Google Scholar
22. Riou, D. and Férey, G., J. Solid State Chem., 120 (1995) 137.Google Scholar
23. Riou, D. and Férey, G., Inorg. Chem., 34 (1995) 6250.Google Scholar
24. Riou, D. and Férey, G., J. Solid State Chem., 124 (1996) 151.Google Scholar
25. Nazar, L. F., Koene, B. E., and Britten, J. F., Chem. Mater., 8 (1996) 327.Google Scholar
26. Zhang, Y., O'Connor, C. J., Clearfield, A., and Haushalter, R. C., Chem. Mater., 8 (1996) 595.Google Scholar
27. Zhang, Y., Haushalter, R. C., and Clearfield, A., J. Chem. Soc, Chem. Commun., (1996) 1055. Google Scholar
28. Zhang, Y., DeBord, J. R. D., O'Connor, C. J., Haushalter, R. C., Clearfield, A., and Zubieta, J., Angew. Chem. Int. Ed. Engl., 35 (1996) 989.Google Scholar
29. Chen, R., Zavalij, P., and Whittingham, M. S., Chem Mater, 8 (1996) 1275.Google Scholar
30. Chen, R., Chirayil, T., and Whittingham, M. S., Proceedings of the 10th International Symposium on Solid State Ionics, Singapore, December 1995. Solid State Ionics, 86–88 (1996) 1.Google Scholar
31. Pernet, M., Joubert, J. C., and Ferrand, B., Solid State Communications, 16 (1975) 503.Google Scholar
32. Chen, R., Zavalij, P. Y., and Whittingham, M. S., Chem. Mater., (1997) in press.Google Scholar
33. Shannon, R. D. and Calvo, C., J. Solid State Chem., 6 (1973) 538.Google Scholar
34. Zhang, F., Zavalij, P. Y., and Whittingham, M. S., Mater. Res. Bull., (1997) in press.Google Scholar
35. Galy, J., J. Solid State Chem., 100 (1992) 229.Google Scholar
36. Zhang, F., Zavalij, P. Y., and Whittingham, M. S., This volume, (1997)Google Scholar