Hostname: page-component-586b7cd67f-g8jcs Total loading time: 0 Render date: 2024-11-25T15:37:27.825Z Has data issue: false hasContentIssue false

Hydrogen Stability in Hydrogenated Amorphous Silicon-Based Alloys

Published online by Cambridge University Press:  21 February 2011

W. Beyer
Affiliation:
Institut für Schicht- und Ionentechnik (ISI-PV), Forschungszentrum Jülich, D-S170 Jülich, Germany
J. Herion
Affiliation:
Institut für Schicht- und Ionentechnik (ISI-PV), Forschungszentrum Jülich, D-S170 Jülich, Germany
H. Wagner
Affiliation:
Institut für Schicht- und Ionentechnik (ISI-PV), Forschungszentrum Jülich, D-S170 Jülich, Germany
U. Zastrow
Affiliation:
Institut für Schicht- und Ionentechnik (ISI-PV), Forschungszentrum Jülich, D-S170 Jülich, Germany
Get access

Abstract

The thermal stability of hydrogen in amorphous silicon-based alloy films was studied by deuterium/hydrogen interdiffusion and hydrogen effusion experiments. Depending on the film structure, hydrogen stability is limited by hydrogen surface desorption or hydrogen diffusion. The hydrogen surface desorption energy is found to decrease with rising germanium content and to increase with rising nitrogen and carbon content. At T = 400°C, hydrogen diffusion is found to proceed in the germanium subnetwork for a-SiGe alloys and in the silicon subnetwork for a-SiN and a-SiC alloys.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Carlson, D.E. and Magee, C.W., Appl. Phys. Lett. 33, 81 (1978).CrossRefGoogle Scholar
[2] Street, R.A., Tsai, C.C., Kakalios, J. and Jackson, W.B., Philos. Mag. B 56, 305 (1987).CrossRefGoogle Scholar
[3] Beyer, w., Physica B 170 (1991), in print.Google Scholar
[4] Beyer, W., Herion, J., Wagner, H. and Zastrow, U., Philos. Mag. B 63, 269 (1991).Google Scholar
[5] Beyer, W., in Tetrahedrallv-Bonded Amorphous Semiconductors, edited by Adler, D. and Fritzsche, H. (Plenum, New York, 1985) p. 129 CrossRefGoogle Scholar
[6] Beyer, W. and Mell, H., in Disordered Semiconductors, edited by kastner, M.A., Thomas, G.A. and Ovshinsky, S.R. (Plenum, New York, 1987) p. 641.Google Scholar
[7] Beyer, W. and Wagner, H., J.Appl. Phys. 53, 8745 (1982).CrossRefGoogle Scholar
[8] Huber, K.P., in AIP Handbook of Physics, edited by Grey, D.E. (McGraw-Hill, New York, 1972) p. 7168.Google Scholar
[9] Redhead, P.A., Vacuum 12, 203 (1962).Google Scholar