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Hybrid Organic-Inorganic Systems Derived from Organotin Nanobuilding Blocks

Published online by Cambridge University Press:  10 February 2011

F. O. Ribot ,
C. Eychenne-Baron ,
F. Banse  and
C. Sanchez
F. O. Ribot
Affiliation:
Laboratoire de Chimie de la Matiàre Condensáe - Universitá P. et M. Curie / CNRS, 4 Place Jussieu, 75252 Paris, France
C. Eychenne-Baron
Affiliation:
Laboratoire de Chimie de la Matiàre Condensáe - Universitá P. et M. Curie / CNRS, 4 Place Jussieu, 75252 Paris, France
F. Banse
Affiliation:
Laboratoire de Chimie de la Matiàre Condensáe - Universitá P. et M. Curie / CNRS, 4 Place Jussieu, 75252 Paris, France
C. Sanchez
Affiliation:
Laboratoire de Chimie de la Matiàre Condensáe - Universitá P. et M. Curie / CNRS, 4 Place Jussieu, 75252 Paris, France
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Abstract

A new synthesis of the macro-cation {(BuSn)12O4(OH)6}2 is described from commercially available and easy to handle BuSnO(OH) and p-toluene sulfonic acid. A crystalline compound, {(BuSn)12O4(OH)6}(O3SC6H4CH3)2.C4H8O2, is obtained. It can react with tetramethylammonium hydroxide to yield the more versatile composition: {(BuSn)12O4(OH)6}(OH)2. The macro-cations are then used as nanobuilding blocks and assembled in rosary-like structures by carboxyterminated poly(ethyleneglycol). The resulting system can be pictured as hybrid organic-inorganic alternated block co-polymers. Characterizations were performed with 119Sn NMR (solution and solid state), 13C CP-MAS NMR and FT-IR.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 435: Symposium V – Better Ceramics Through Chemistry VII , 1996 , 43
Copyright
Copyright © Materials Research Society 1996

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