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High-Temperature Potentiometric NO2 and CO Sensors Based on Stabilized Zirconia with Oxide Sensing Electrodes

Published online by Cambridge University Press:  11 February 2011

E. Di Bartolomeo
Affiliation:
Department of Chemical Science and Technology, University of Rome Tor Vergata, Via della Ricerca Scientifica, 00133 Rome, Italy
M. L. Grilli
Affiliation:
Department of Chemical Science and Technology, University of Rome Tor Vergata, Via della Ricerca Scientifica, 00133 Rome, Italy
N. Kaabbuathong
Affiliation:
Department of Chemical Science and Technology, University of Rome Tor Vergata, Via della Ricerca Scientifica, 00133 Rome, Italy
E. Traversa
Affiliation:
Department of Chemical Science and Technology, University of Rome Tor Vergata, Via della Ricerca Scientifica, 00133 Rome, Italy
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Abstract

This paper reports the efforts made in our laboratory to develop electrochemical sensors that might detect NO2 and CO at high temperatures for On Board Diagnostic (OBD) application. The non-Nernstian behaviour of zirconia-based electrochemical NO2 sensors with various oxides as sensing electrodes was studied in the temperature range 450–700°C. Both pellets and tape-casted layers (150 μm of thickness) of yttria-stabilized zirconia (YSZ) were used for fabrication of the sensors. Pt electrodes were painted on both sides of the pellets or as two parallel fingers on one face of the layers. One of the Pt electrodes was covered with a thick-film oxide electrode. Various oxides were tested as sensing electrodes, either p- or n-type semiconductors, including WO3 and LaFeO3. The role of ionic conductivity of the oxide electrodes was investigated using Sr-doped perovskite-type oxides, such as LaxSr1-xFeO3, a mixed ionic-electronic conductor. The sensors were tested as potentiometric and amperometric devices. The performance of these devices was promising: fast and stable responses to different NO2 concentrations (20–1000 ppm in synthetic air) were observed at high temperatures. The role of the metallic electrodes is also studied. The sensing mechanism of the sensors is discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

1. Oishi, K., in Proceedings of the Electrochemical Society Symposium, Vol. 93–7, Proceedings of the Symposium on Chemical Sensors II, Eds. Butler, M., Ricco, A., and Yamazoe, N., (The Electrochemical Society, Pennington, NJ, 1993) p. 443.Google Scholar
2. Shimizu, Y., Maeda, K., Chem. Lett., 117 (1996).Google Scholar
3. Shimizu, Y. and Maeda, K., Sensors and Actuators B 52, 84 (1998).Google Scholar
4. Di Bartolomeo, E., Traversa, E., Baroncini, M., Kotzeva, V. and Kumar, R.V., J. Eur. Ceram. Soc., 20, 2691 (2000).Google Scholar
5. Miura, N., Shirahishi, T., Shimanoe, K., Yamazoe, N., Electrochem. Commun., 2, 77 (2000).Google Scholar
6. Shimizu, Y. and Yamashita, N., Sensors and Actuators B, 64, 102 (2000).Google Scholar
7. Miura, N., Kurosawa, H., Hasei, M., Lu, G., and Yamazoe, N., Solid State Ionics, 86–88, 1069 (1996).Google Scholar
8. Lu, G., Miura, N. and Yamazoe, N., J. Mater. Chem., 7, 1445 (1997).Google Scholar
9. Lu, G., Miura, N., and Yamazoe, N., Ionics 4, 16 (1998).Google Scholar
10. Miura, N., Lu, G., Ono, M. and Yamazoe, N., Solid State Ionics 117, 283 (1999).Google Scholar
11. Lu, G., Miura, N., and Yamazoe, N., Sensors and Actuators B, 65, 125 (2000).Google Scholar
12. Miura, N., and Yamazoe, N., in Sensors Update, Vol. 6, Eds. Baltes, H, Göpel, W. and Hesse, J., (WILEY-VCH, Weinheim, Germany, 2000) p. 191.Google Scholar
13. Yoon, J.W., Grilli, M.L., Di Bartolomeo, E., Polini, R., and Traversa, E., Sensors and Actuators B 76, 483 (2001).Google Scholar
14. Grilli, M.L., Di Bartolomeo, E. and Traversa, E., J. Electrochem. Soc., 148, p. H98 (2001).Google Scholar
15. Grilli, M. L., Kaabbuathong, N., Dutta, A., Di Bartolomeo, E. and Traversa, E., J. Ceram. Soc. Jp, 110 [3], 159 (2002).Google Scholar
16. Miura, N., Zhuiykov, S., Ono, T., Hasei, M., and Yamazoe, N., Sensors and Actuators B, 83, 222 (2002).Google Scholar
17. Hibino, T., Hashimoto, A., Kakimoto, S., and Sano, M., J. Electrochem. Soc., 148, p. H1 (2001).Google Scholar
18. Brosha, E.L., Mukundan, R., Brown, D.R., Garzon, F.H., Visser, J.H., Zanini, M., Zhou, Z., Lothetis, E. M., Sensors and Actuators B, 69, 171 (2000).Google Scholar
19. Brosha, E.L., Mukundan, R., Brown, D.R., Garzon, F.H., Visser, J.H., Solid State Ionics 148, 61 (2002).Google Scholar
20. Ménil, F., Coillard, V., Lucat, C., Sensors Actuators B 67, 1 (2000).Google Scholar
21. Shimizu, Y., Nishi, H., Suzuki, H., and Maeda, K., Sensors Actuators B, 65, p. 141 (2000).Google Scholar
22. Wachsman, E. D. and Jayaweera, P., in Solid State Ionic Devices II – Ceramic Sensors, Eds. Wachsman, E.D., Weppner, W., Traversa, E., Liu, M., Vanysek, P., and Yamazoe, N., (The Electrochem. Soc. Proc. Series, Pennington, NJ, 2001) p. 298.Google Scholar
23. Hibino, T., Hashimoto, A., Inoue, T., Tokuno, J., Yoshida, S. and Sano, M., Science, 288, 2031 (2000).Google Scholar
24. Hibino, T., Hashimoto, A., Inoue, T., Tokuno, J., Yoshida, S. and Sano, M., J. Electrochem Soc., 148 (6) A544 (2001).Google Scholar
25. Hibino, T., Hashimoto, A., Yano, M., Suzuki, M., Yoshida, S. and Sano, M., J. Electrochem Soc., 149 (2) A133 (2002).Google Scholar
26. Akiyama, M., Zhang, Z., Tamaki, J., Miura, N., Yamazoe, N. and Harada, T., Sensors and Actuators B, 13–14, 619 (1993).Google Scholar
27. Inoue, T., Ohtsuka, K., Yoshida, Y., Matsuura, Y. and Kajiyama, Y., Sensors and Actuators B, 24–25, 388 (1995).Google Scholar
28. Traversa, E., Sadaoka, Y., Carotta, M. C., and Martinelli, G., Sensors and Actuators B, 65, 181185 (2000).Google Scholar
29. Traversa, E., Sakamoto, M., and Sadaoka, Y., J. Am. Ceram. Soc., 79, 1401 (1996)Google Scholar
30. Dutta, A., Kaabbuathong, N., Grilli, M.L., Di Bartolomeo, E. and Traversa, E., J. Electrochem Soc., in press (Feb. 2003).Google Scholar