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High-Performance Amorphous Silicon Emitter for Crystalline Silicon Solar Cells

Published online by Cambridge University Press:  01 February 2011

T.H. Wang
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401,USA
E. Iwaniczko
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401,USA
M.R. Page
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401,USA
Q. Wang
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401,USA
D.H. Levi
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401,USA
Y. Yan
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401,USA
Y. Xu
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401,USA
H.M. Branz
Affiliation:
National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, CO 80401,USA
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Abstract

Thin hydrogenated amorphous silicon (a-Si:H) layers deposited by hot-wire chemical vapor deposition (HWCVD) are studied for use as the emitter in silicon heterojunction (SHJ) solar cells on p-type crystalline silicon wafers. Low interface recombination velocity and high open-circuit voltage are achieved by a low substrate temperature (<150°C) intrinsic a-Si:H deposition which ensures immediate amorphous silicon deposition. This is followed by deposition of n-type a-Si:H at a higher temperature (>200°C) which improves dopant activation and other properties. A prolonged atomic H pretreatment to clean the c-Si surface is actually detrimental because it creates additional defects in the c-Si lattice. However, a brief H pretreatment is beneficial and may render the intrinsic interlayer unnecessary. The n-type a-Si:H thickness must be limited to ~5 nm to minimize current loss, because the phosphorous doped a-Si:H layer has significant absorption in the usable solar spectrum. Using the optimized a-Si:H emitter, we obtain efficiency of nearly 17% on planar float-zone (FZ) silicon and 15% on planar Czochralski (CZ) silicon substrates with aluminum back-surface-field (Al-BSF) and contacts.

Type
Research Article
Copyright
Copyright © Materials Research Society 2005

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References

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