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Growth of Gan on Porous Sic Substrates by Plasma-Assisted Molecular Beam Epitaxy

Published online by Cambridge University Press:  01 February 2011

C. K. Inoki
Affiliation:
Department of Physics, University at Albany, SUNY, Albany, NY 12222
T. S. Kuan
Affiliation:
Department of Physics, University at Albany, SUNY, Albany, NY 12222
C. D. Lee
Affiliation:
Department of Physics, Carnegie Mellon University, Pittsburgh, PA 15213
Ashutosh Sagar
Affiliation:
Department of Physics, Carnegie Mellon University, Pittsburgh, PA 15213
R. M. Feenstra
Affiliation:
Department of Physics, Carnegie Mellon University, Pittsburgh, PA 15213
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Abstract

We have explored the growth of GaN on porous SiC substrates by plasma-assisted molecular beam epitaxy. The porous 4H- and 6H-SiC(0001) substrates used in this study contain 10 to 100-nm sized pores and a thin skin layer at the surface. This skin layer was partially removed prior to the growth by H-etching. Transmission electron microscopy (TEM) observations indicate that the epitaxial GaN growth initiates from the surface areas between pores, and the exposed surface pores tend to extend into GaN as open tubes and trap Ga droplets. Plan-view TEM observations indicate that the GaN layers grown on porous substrates contain fewer dislocations than layers grown on non-porous substrates by roughly a factor of two. The GaN layers grown on a porous SiC substrate were also found to be mechanically more relaxed than those grown on non-porous substrates; electron diffraction patterns indicate that the former are free of misfit strain or are even in tension after cooling to room temperature.

Type
Research Article
Copyright
Copyright © Materials Research Society 2002

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References

1. Saddow, S. E., Mynbaeva, M., Choyke, W. J., Bai, S., Melnychuk, G., Koshka, Y., Dimitriev, V. and Wood, C. E. C., Materials Science Forum 353-356, 115 (2001).Google Scholar
2. Mynbaeva, M., Titkov, A., Kryzhanovski, A., Ratnikov, V., Huhtinen, H., Laiho, R. and Dmitriev, V., Appl. Phys. Lett. 76, 1113 (2000)Google Scholar
3. Mynbaeva, M., Titkov, A., Kryzhanovski, A., Kotousova, I., Zubrilov, A. S., Ratnikov, V. V., Davydov, V. Yu., Kuznetsov, N. I., Mynbaev, K., Tsvetkov, D. V., Stepanov, S., Cherenkov, A., and Dmitriev, V., MRS Internet J. Nitride Semicond. Res. 4, 14 (1999)Google Scholar
4. Mynbaeva, M., Titkov, A., Kryzhanovski, A., Zubrilov, A., Ratnikov, V., Davydov, V., Kuznetsov, N., Mynbaev, K., Stepanov, S., Cherenkov, A., Kotousova, I., Tsvetkov, D., and Dmitriev, V., Mat. Res. Soc. Symp. Vol. 595, W2.7 (2000).Google Scholar
5. Melnychuk, G., Mynbaeva, M., Rendakova, S., Dmitriev, V. and Saddow, S. E., Mat. Res. Soc. Symp. Vol. 622, T4.2 (2000).Google Scholar
6. Li, X., Kim, Y. -W., Bohn, P. W., and Adesida, I., Appl. Phys. Lett. 80, 980 (2002)Google Scholar
7. Shor, J. S., Grimberg, I., Weiss, B. -Z. and Kurtz, A. D., Appl. Phys. Lett. 62, 2836 (1993)Google Scholar
8. Sagar, A., Lee, C. D., Feenstra, R. M., Inoki, C. K., and Kuan, T. S., submitted to J. Appl. Phys. The increased temperature of porous SiC is consistent with the well known characteristic of porous Si that its thermal conductivity is 1-2 orders of magnitude lower than that of nonporous Si (see, e.g., Perichon, S. et al., Diffus. Defect Data B, Solid State Phenom. 80-81, 417 (2001)).Google Scholar
9. Ramachandran, V., Brady, M. F., Smith, A. R. and Feenstra, R. M., J. Electron. Mat. 27, 308 (1998)Google Scholar
10. Lee, C. D., Sagar, A., Feenstra, R. M., Inoki, C. K., Kuan, T. S., Sarney, W. L., and Salamanca-Riba, L., Appl. Phys. Lett. 79, 3428 (2001)Google Scholar
11. Lee, C. D., Feenstra, R. M., Shigiltchoff, O., Devaty, R. P. and Choyke, W. J., MRS Internet J. Nitride Semicond. Res. 7, 2 (2002)Google Scholar
12.It is possible that the SiC lattice constant changes when the material is made porous. For example, porous Si is found to have a larger lattice constant than nonporous Si (Barla, K., Herino, R., Bomchil, G., and Pfister, J. C., J. Cryst. Growth 68, 727 (1984)).Google Scholar
13. Waltereit, P., Brandt, O., Trampert, A., Ramsteiner, M., Reiche, M., Qi, M., and Ploog, K. H., Appl. Phys. Lett. 74, 3660 (1999)Google Scholar