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Growth and Structure of Carbide Nanorods

Published online by Cambridge University Press:  10 February 2011

Charles M. Lieber
Affiliation:
Department of Chemistry and Division of Applied Sciences Harvard University, Cambridge, MA 02138
Eric W. Wong
Affiliation:
Department of Chemistry and Division of Applied Sciences Harvard University, Cambridge, MA 02138
Hongjie Dai
Affiliation:
Department of Chemistry and Division of Applied Sciences Harvard University, Cambridge, MA 02138
Benjamin W. Maynor
Affiliation:
Department of Chemistry and Division of Applied Sciences Harvard University, Cambridge, MA 02138
Luke D. Burns
Affiliation:
Department of Chemistry and Division of Applied Sciences Harvard University, Cambridge, MA 02138
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Abstract

Recent research on the growth and structure of carbide nanorods is reviewed. Carbide nanorods have been prepared by reacting carbon nanotubes with volatile transition metal and main group oxides and halides. Using this approach it has been possible to obtain solid carbide nanorods of TiC, SiC, NbC, Fe3C, and BCx having diameters between 2 and 30 nm and lengths up to 20 µm. Structural studies of single crystal TiC nanorods obtained through reactions of TiO with carbon nanotubes show that the nanorods grow along both [110] and [111] directions, and that the rods can exhibit either smooth or saw-tooth morphologies. Crystalline SiC nanorods have been produced from reactions of carbon nanotubes with SiO and Si-iodine reactants. The preferred growth direction of these nanorods is [111], although at low reaction temperatures rods with [100] growth axes are also observed. The growth mechanisms leading to these novel nanomaterials have also been addressed. Temperature dependent growth studies of TiC nanorods produced using a Ti-iodine reactant have provided definitive proof for a template or topotactic growth mechanism, and furthermore, have yielded new TiC nanotube materials. Investigations of the growth of SiC nanorods show that in some cases a catalytic mechanism may also be operable. Future research directions and applications of these new carbide nanorod materials are discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

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References

REFERENCES

1. Ruoff, R. S., Nature 372, 731 (1994).Google Scholar
2. Guerret-Piecourt, C., Bouar, Y. Le, Loiseau, A., Pascard, H., Nature 372, 761 (1994).Google Scholar
3. Tsang, S. C., Chen, Y. K., Harris, P. J., Green, M. L. H., Nature 372, 159 (1994).Google Scholar
4. Ajayan, P. M. and lijima, S., Nature 361, 333 (1993).Google Scholar
5. Dai, H., Wong, E. W., Lu, Y. Z., Fan, S., Lieber, C. M., Nature 375, 769 (1995).Google Scholar
6. Ebbesen, T. W. and Ajayan, P. M., Nature 358, 220 (1992).Google Scholar
7. Colbert, D. T., Zhang, J., McClure, S. M., Nikolaev, P., Chen, Z., Hafner, J. H., Owens, D. W., Kotula, P. G., Carter, C. B., Weaver, J. H., Rinzler, A. G., Smalley, R. E., Science 266, 1218 (1994).Google Scholar
8. Storms, E. K., The Refractory Carbides, (Academic Press, New York, 1967), p. 1.Google Scholar
9. Zhou, D. and Seraphin, S., Chem. Phys. Lett. 222, 233 (1994).Google Scholar
10. Wang, L., Wada, H., Allard, L. F., J. Mater. Res. 7, 148 (1992).Google Scholar
11. Bootsma, G. A., Knippenberg, W. F., Verspui, G., J. Cryst. Growth 11, 297 (1971).Google Scholar
12. Wong, E. W., Burns, L., Lieber, C. M., manuscript in preparation.Google Scholar