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Growth and Stability of MgO/NiO Multilayered Films on Single Crystal NiO(100)

Published online by Cambridge University Press:  15 February 2011

S. Imaduddin  and
R. J. Lad
S. Imaduddin
Affiliation:
Laboratory for Surface Science and Technology, 5764 Sawyer Research Center, University of Maine, Orono, ME 04469-5764
R. J. Lad
Affiliation:
Laboratory for Surface Science and Technology, 5764 Sawyer Research Center, University of Maine, Orono, ME 04469-5764
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Abstract

The less than 1% lattice mismatch between MgO and NiO makes them ideal candidates for investigating the growth and stability of multilayered oxide films. Ultra-thin multilayers composed of alternating films of MgO and NiO were deposited onto a stoichiometric NiO(100) single crystal substrate at 250°C by evaporating Mg and Ni in 5×10−7 Torr of O2, respectively. The structure of these multilayers was determined using LEED. Reactivity and chemical composition studies of the MgO/NiO interfaces were carried out using XPS and UPS. The MgO/NiO multilayers grow epitaxially on NiO(100), as evidenced by LEED. XPS and UPS analysis indicates attenuation of the NiO or MgO peaks during growth which is consistent with discrete layering. Chemical analysis also reveals negligible intermixing of the MgO and NiO layers during deposition. Results pertaining to the thermal stability of the multilayers show that UHV annealing above 750°C results in significant diffusion of MgO into the NiO(100) substrate.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 401: Symposium G – Epitaxial Oxide Thin Films II , 1995 , 507
Copyright
Copyright © Materials Research Society 1996

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References

[1] Lad, R.J., Surface Review and Letters 2, 109 (1995).Google Scholar
[2] Henrich, V.E. and Cox, P.A., The Surface Science of Metal Oxides, (Cambridge University Press, Great Britain, 1994).Google Scholar
[3] Imaduddin, S., Davidson, A.M. and Lad, R.J., Mat. Res. Soc. Symp. Proc. Vol.357, 177 (1995).Google Scholar
[4] Wu, M.C., Corneille, J.A., Estrada, C.A., Goodman, D.W., Chem. Phys. Lett. 182, 472 (1991).Google Scholar
[5] Burke, M. L. and Goodman, D.W., Surf. Sci. 311, 17 (1994).Google Scholar
[6] Peacor, S.D. and Hibma, T., Surf. Sci. 310, 11 (1994).Google Scholar
[7] Carey, M.J., Berkowitz, A.E., Borchers, J.A., Erwin, R.W., Phys. Rev. B 47, 9952 (1993).Google Scholar
[8] Lind, D.M., Berry, S.D., Chern, G., Mathias, H., Testardi, L.R., Phys. Rev. B 45, 1838 (1992).Google Scholar
[9] Chambers, S.A., Gao, Y. and Liang, Y., Surf. Sci. 339, 297 (1995).Google Scholar
[10] Kado, T. and Yamada, T., J. Appl. Phys. 77, 6651 (1995).Google Scholar
[11] Kelpin, Kristallhandel, Im Schilling 18, Leimen bei Heidelberg, Germany.Google Scholar
[12] Imaduddin, S. and Lad, R.J., Surf. Sci. 290, 35 (1993).Google Scholar
[13] Tjeng, L.H., Vos, A.R. and Sawatzky, G.A., Surf. Sci. 235, 269 (1990).Google Scholar
[14] Seah, M.P. and Dench, W.A., NPL Report Chem. 82, (1978).Google Scholar
[15] Legg, K.O., Prutton, M. and Kinniburgh, C.G., J. Phys. C7, 4236 (1974).Google Scholar
[16] Welton-Cook, M.R. and Prutton, M., J. Phys. C13, 3993 (1980).Google Scholar
[17] Reed, T.B., Free Energy of Formation for Binary Compounds (MIT Press, 1971).Google Scholar
[18] Levin, E.M., Robbins, C.R., McMurdie, H.F., Phase Diagrams for Ceramists, edited by Reser, M.K. (The American Ceramic Society, Ohio, 1964).Google Scholar
[19] Imaduddin, S. and Lad, R.J.(in preparation).Google Scholar