Hostname: page-component-78c5997874-8bhkd Total loading time: 0 Render date: 2024-11-20T03:46:29.814Z Has data issue: false hasContentIssue false

Glass/Water Reaction with and without Bentonite Present - Experiment and Model

Published online by Cambridge University Press:  28 February 2011

B. Grambow
Affiliation:
Hahn-Meitner-Institut für Kernforschung GmbH, 1 Berlin-39, Glienickerstr. 100, FRG
H. P. Hermansson
Affiliation:
StudsviK Energiteknik AB, S-61182 Nyköping, Sweden
I. K. Björner
Affiliation:
StudsviK Energiteknik AB, S-61182 Nyköping, Sweden
L. Werme
Affiliation:
Swedish Nuclear Fuel and Waste Management CO. SKB, Box 5864 S-10248 Stockholm, Sweden
Get access

Extract

In nuclear waste repository design bentonite has been included as part of the backfill for its sorbtive capacity and low water permeability. Nevertheless, it cannot keep the waste form dry once intrusion of groundwater has occured [1]. Leach experiments [2], [3] with the radioactive nuclear waste form borosilicate glass JSS-A have been performed with and without bentonite present to provide a database which allows the long term stability of the glass in aqueous environment to be forecasted and the chemical effects of bentonite to be studied.

Type
Research Article
Copyright
Copyright © Materials Research Society 1985

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Pigford, T. H., et al.; Waste Isolation Systems Panel, National Research Council, National Academy Press, Washington, D.C. (1983)Google Scholar
2. Hermansson, H. P., Björner, I. K., Christensen, H., and Yokoyama, H.; JSS-Project - Technical Report 84-01, SKB, Stockholm, Sweden (1985)Google Scholar
3. Hermansson, H. P. et al. (1985), this volumeGoogle Scholar
4. Grambow, B., in Advances in Ceramics 8, edited by Wicks, G., Ross, W. (Am. Ceram. Soc. Columbus, Ohio, 1984) pp. 474481 Google Scholar
5. Strachan, D.M., Krupka, K.M., Grambow, B., Nucl. Chem. Waste 5, 8799 (1984)CrossRefGoogle Scholar
6. Grambow, B., in Scientific Basis for Nuclear Waste Management VIII edited by Jantzen, C. M., Stone, J. A., Ewing, R. C., (Elsevier Science Publishers, New York, 1985) (in press)Google Scholar
7. Kittrick, J. A., in ACS Symposium Series 93, edited by Jenne, E.A., Am. Chem. Soc. (1919)Google Scholar
8. Christensen, H., Hermansson, H. P., ClarK, D. E., Werme, L., in Advances in Ceramics 8, edited by Wicks, G. and Ross, W., (Am. Ceram. Soc.), pp. 346–357 (1984)Google Scholar
9. Nogues, J.L., Vernaz, E.Y., Jacquet-Francillon, N., Pasquini, S., in Scientific Basis for Nuclear Waste Management VIII, eds. Jantzen, C. M., Stone, J. A., Ewing, R. C., (Elsevier Science Publishers, New York, 1985) (in press)Google Scholar
10. Parkhurst, D. L., Thorstensen, D. C., Plummer, L. N., (original PHREEQE) Water Resources Investigations 80–96 (U.S. Geol. Surv. Reston Virginia, 1980) extension to run precipitation controlled reaction by P. Offermann, HMI; updated with MINTEQ - database by W. Howden, K. Kruppka, PNL (1984)Google Scholar
11. Müller Vonmoos, M., Kahr, G., Technischer Bericht 83-12, Nagra, Baden (1983)Google Scholar
12. Lerman, A., Mackenzie, F. T., Bricker, O. P., Earth and Planetary Letters 25, 8288, (1975)CrossRefGoogle Scholar
13. Tardy, Y., Fritz, B., Clay Minerals 16, 361 (1981)CrossRefGoogle Scholar
14. Smellman, M., personal communication, VTT, Finland (1985)Google Scholar
15. Siever, R., Woodford, N., Geo. Cosmochim. Acta, 37, 18511880 (1973)CrossRefGoogle Scholar