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FTIR Characterization Of PZT Nano Fibers Synthesized from Metallo-organic Compounds Using Electrospinning

Published online by Cambridge University Press:  11 February 2011

Yu Wang  and
Jorge J. Santiago-Avilés
Yu Wang
Affiliation:
Department of Electrical and System Engineering, University of Pennsylvania, Philadelphia, PA, 19104
Jorge J. Santiago-Avilés
Affiliation:
Department of Electrical and System Engineering, University of Pennsylvania, Philadelphia, PA, 19104
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Abstract

We have synthesized Pb(Zr0.54Ti0.48)O3 fibers with diameter ranging from 500 nm to several microns using electrospinning and metallo-organics decomposition (MOD) techniques. By a refinement of our electrospinning technique, i.e. by increasing the viscosity of the precursor solution, and by adding a filter to the tip of the syringe, the diameter of synthesized PZT fibers has been reduced to the neighborhood of a hundred nanometers. The complex thermal decomposition was characterized using Fourier-transform infrared (FTIR) spectroscopy and x-ray diffraction (XRD). It was found that alcohol evaporated during electrospinning and that the organic groups had pyrolized before the intermediate pyrochlore phase was formed. There is a good correspondence between XRD and FTIR spectra. It was also found that a thin film of platinum coated on silicon substrate surface not only seems to have catalyzed the phase transformation to PZT but also favored the formation of 110 texture in the synthesized PZT fibers.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 736: Symposium D – Electronics on Unconventional Substrates–Electrotextiles and Giant-Area Flexible Circuits , 2002 , D2.9
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

Hu, J, Odom, T W, Lieber, C,. M, Acc. Chem. Res. 32, 435(1999)Google Scholar
2. Duan, X, Huang, Y, Wangand, J, Lieber, C M, Nature, 409, 66(2001)Google Scholar
3. Pignolet, A., Wang, L., Proctor, M., Levy, F. and Schmid, P. E., J. Appl. Phys. 74, 6625 (1993).Google Scholar
4. Shaw, T. M., Trolier-McKinstry, S., McIntryre, P. C., Annu. Rev. Mater. Sci. 30, 263 (2000).Google Scholar
5. 13. Takeuchi, H and Nakaya, C, Ferroelectrics, 68: 53(1986)Google Scholar
6. Park, H, “PZT Fibers”, ONR Review of Piezoelectric and Electrostrictive Material for Transducer Application, State Colleague, PA, April 22, 1991(1991)Google Scholar
7. Waller, D. J., Safari, A, Card, R. and Toole, M. P. O, J. Am. Ceram. Soc, 73: 3503–3506(1990)Google Scholar
8. Selvaraj, U, Prasadarao, A. V., Komarneni, S., Brooks, K., and Kurtz, S. K., J Mater. Res, 7, 992–996(1992)Google Scholar
9. Meyer, R. Jr, Shrout, T and Yoshikawa, S, J. Am. Ceram. Soc, 81(4)861–68(1998)Google Scholar
10. Wang, Y, Serrano, S, Santiago, J, Mater. Res. Soc. Symp. Proc. Vol 702, 359 (2002)Google Scholar
11. Lipeles, R. A, Coleman, D J, Leung, M S, Mater. Res. Soc. Symp. Proc. Vol 73, 665 (1986)Google Scholar
12 Lin, C-T, Li, L and Webb, J S, Integrated Ferroelectrics, 3 333–341 (1993)Google Scholar
13. Zhu, W, Q Liu, Z., Tse, M S, Tan, H S, J. Mater. Sci.: Mater. in Electro, 6, 369–374 (1995)Google Scholar
14. Li, S, A Condrate, R. Sr, and Spriggs, R M, J. Canadian Ceram. Soc., 57(4), 61 (1988)Google Scholar
15. Park, Y-I, Nagai, M, Miyayama, M, Kudo, T, J. Mater. Sci., 36, 1995–2000 (2001)Google Scholar
16. Wang, Y and Santiago, J, to be publishedGoogle Scholar
17. Kittel, C., Introduction to solid state Physics, 4th ed. p83, John Wiley & Son, New York, 1971.Google Scholar
18. Silverstein, R. M. and Webster, F X Spectrometric Identification of Organic Compound, 6th ed. (John Wiley & Son, New York, 1998), p79.Google Scholar
19. The Aldrich Library of FT-IR spectra, Edition II, Vol. 1–4, Sigma-Aldrich Co., 1997.Google Scholar
20. Bradley, D.C., Rothwell, I., Mehrotra, R. C., Alkoxo and aryloxo derivatives of metals, 2nd eds. (San Diego: Academic Press, 2001), p75.Google Scholar
21. Chen, K C and Mackenzie, J D, Mater. Res. Soc. Symp. Proc. Vol 180, 663 (1990)Google Scholar