Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-17T18:15:14.914Z Has data issue: false hasContentIssue false

Flexible Fast Lithium Ion Conducting Ceramic Electrolyte

Published online by Cambridge University Press:  18 March 2013

Koichi Hamamoto
Affiliation:
Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 2266-98 Shimoshidami Moriyama-ku Nagoya 463-8687 JAPAN
Danila Matveev
Affiliation:
Institute of Solid State Physic Russian Academy of Science, 142432 Chernogolovka, Russia
Toshiaki Yamaguchi
Affiliation:
Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 2266-98 Shimoshidami Moriyama-ku Nagoya 463-8687 JAPAN
Hirofumi Sumi
Affiliation:
Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 2266-98 Shimoshidami Moriyama-ku Nagoya 463-8687 JAPAN
Toshio Suzuki
Affiliation:
Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 2266-98 Shimoshidami Moriyama-ku Nagoya 463-8687 JAPAN
Sergey Bredikhin
Affiliation:
Institute of Solid State Physic Russian Academy of Science, 142432 Chernogolovka, Russia
Yoshinobu Fujishiro
Affiliation:
Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 2266-98 Shimoshidami Moriyama-ku Nagoya 463-8687 JAPAN
Get access

Abstract

Large-area fast lithium ion conducting ceramic thin freestanding sheets was successfully prepared using a sheet forming technique. This ceramic sheet contains the crystalline phase of Li1+x+yAlxTi2-xSiyP3-yO12 with the NASICON type structure. The ceramic sheet showed maximum overall conductivity over 10−3 S cm−1 at room temperature. And, the developed thin ceramic sheet has sufficient flexibility against bending stress. Because a thin large-area ceramic electrolyte sheet was prepared using less energy compared with a conventional glass casting method, it is suitable for practical use.

Type
Articles
Copyright
Copyright © Materials Research Society 2013

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Abraham, K. M. and Jian, Z., Electrochem. Soc., 143, 1 (1996).CrossRefGoogle Scholar
Peng, Z., Freunberger, S. A., Chen, Y. and Bruce, P. G., Science, 337, 563 (2012).CrossRefGoogle Scholar
Kraytsberg, A. and Ein-Eli, Y., Journal of Power Sources, 196, 886 (2011).CrossRefGoogle Scholar
Wang, Y. and Zhou, H., Journal of Power Sources, 195, 358 (2010).CrossRefGoogle Scholar
Armand, M., Tarascon, J.-M., Nature, 451, 652 (2008).CrossRefGoogle Scholar
Aono, H., Sugimoto, E., Sadaoka, Y., Imanaka, N. and Adachi, G., J. Electrochem. Soc., 136, 590 (1989).CrossRefGoogle Scholar
Aono, H., Sugimoto, E., Sadaoka, Y., Imanaka, N. and Adachi, G., Chem. Lett., 1990, 1825 (1990).CrossRefGoogle Scholar
Fu, J., Solid State Ionics, 96, 195 (1997).CrossRefGoogle Scholar
Fu, J., Solid State Ionics, 104, 191 (1997).CrossRefGoogle Scholar
Fu, J., J. Mater. Sci., 33, 1549 (1998).CrossRefGoogle Scholar
Thokchom, J. S. and Kumar, B., Solid State Ionics, 177, 727 (2006).CrossRefGoogle Scholar
Thokchom, J. S. and Kumar, B., J. Electrochem. Soc., 154, A331 (2007).CrossRefGoogle Scholar
Thokchom, J. S., Gupta, N., and Kumar, B., J. Electrochem. Soc., 155, A915 (2008).CrossRefGoogle Scholar
Puech, L., Cantau, C., Vinatier, P., Toussaint, G. and Stevens, P., Journal of Power Sources, 214, 330 (2012).CrossRefGoogle Scholar
Wong, S., Newman, P. J., Best, A. S., Nairn, K. M., MacFarlane, D. R. and Forsyth, M., J. Mater. Chem., 8, 2199 (1998).CrossRefGoogle Scholar