Hostname: page-component-586b7cd67f-dlnhk Total loading time: 0 Render date: 2024-11-25T17:43:17.970Z Has data issue: false hasContentIssue false

Excimer Laser Induced Photochemistry of Silane-Ammonia Mixtures

Published online by Cambridge University Press:  25 February 2011

J. M. Jasinski
Affiliation:
IBM Research Division, Thomas J.Watson Research Center, Yorktown Heights, NY 10598
D. B. Beach
Affiliation:
IBM Research Division, Thomas J.Watson Research Center, Yorktown Heights, NY 10598
R. D. Estes
Affiliation:
IBM Research Division, Thomas J.Watson Research Center, Yorktown Heights, NY 10598
Get access

Abstract

Steady-state and time resolved molecular beam sampling mass spectrometry have been used to study the ArF excimer laser induced photochemistry of silaneammonia mixtures at 193 nm. Under both steady state and single laser shot conditions, products as complicated as tetraaminosilane are formed promptly. A mechanism which accounts for the formation of all observed products is proposed and evaluated.

Type
Research Article
Copyright
Copyright © Materials Research Society 1989

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Jasinski, J. M. and Meyerson, B. S., J. Appl. Phys., 61, 431 (1987), and references therein.Google Scholar
2. Clark, J. H. and Anderson, R. G., Appl. Phys. Lett., 32, 46 (1978).Google Scholar
3. Okabe, H., Photochemistry of Small Molecules, (Wiley, New York, 1978), p. 269.Google Scholar
4. Mihelcic, D., Schubert, V., Schindler, R. N. and Potzinger, P., J. Phys. Chem., 81, 1543 (1977).Google Scholar
5. Chu, J. O. and Jasinski, J. M., unpublished.Google Scholar
6. Smith, D. L., Alimonda, A., Chen, C., Jackson, W. and Wacker, B., Proceedings of the Materials Research Society Spring Meeting, Reno, NV, 1988.Google Scholar
7. Wu, C., J. Phys. Chem., 91, 5054, 1987.Google Scholar
8. Hinsberg, W. D., Houle, F. A. and Bunker, D. L., “MSIMPC - An Interactive Discrete Chemical Mechanism Simulator for the IBM PC”, IBM Research Report, RJ5855, 1987.Google Scholar
9. Many of the known rate constants can be found in: Becerra, R. and Walsh, R., J. Phys. Chem., 91, 5765 (1987), as well as in reference 3.Google Scholar