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Evaluation of The Catalytic Activity of A High Surface Area, Regular, Porous Solid Formed From The Clusters of Clusters, MII4O[(CO)9Co3CCO2]6, M = Co, Zn

Published online by Cambridge University Press:  25 February 2011

Wei Cen ,
Thomas P. Fehlner ,
Zbigniew Kalenik  and
Eduardo E. Wolf
Wei Cen
Affiliation:
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556
Thomas P. Fehlner
Affiliation:
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556
Zbigniew Kalenik
Affiliation:
Department of Chemical Engineering, University of Notre Dame, Notre Dame, IN 46556
Eduardo E. Wolf
Affiliation:
Department of Chemical Engineering, University of Notre Dame, Notre Dame, IN 46556
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Abstract

The discrete molecular clusters of clusters, M1140[(CO)9Co3CCO2]6, M = Co, Zn undergo thermolysis with the production of highly porous solid materials. Evaluation of the catalytic properties of these materials has been investigated using the hydrogenation of 1,3- butadiene as a test reaction. These experiments suggest it is the unique structure of the porous materials that is responsible for the high activities and the selectivities observed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 286: Symposium J – Nanophase and Nanocomposite Materials , 1992 , 45
Copyright
Copyright © Materials Research Society 1993

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References

REFERENCES

1. Cen, W., Haller, K. W., Fehlner, T. P., Inorg. Chem. 30, 3120 (1991). W. Cen, K. 3. Haller, T. P. Fehlner, Inorg. Chem. 32, 0000 (1993).Google Scholar
2. Cen, W., Ladna, B., Fehlner, T. P., Miller, A. E. and Yue, D., J. Organometal. Chem. 000, 0000 (1993).Google Scholar