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Eu and Yb Excitation Mechanisms in ZnS, CaS, SrS and InP
Published online by Cambridge University Press: 21 February 2011
Abstract
The role of the excitonic excitation mechanism of the rare earth (RE) intra-shell emission is discussed. Two cases are analyzed. For Yb ion in InP 4f-4f emission of Yb3+ is induced by energy transfer from bound exciton state to the RE core state. For Eu in CaS and SrS RE emission is induced by carrier trapping directly to the excited state of Eu2+ ion. Also in this case the intermediate excitonic state may participate in RE excitation, as suggested by some experimental results.
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- Copyright © Materials Research Society 1993