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Ethylene Polymerization via Metallocenes: An Experimental Study

Published online by Cambridge University Press:  16 March 2015

Ramiro Infante-Martínez ,
Enrique Saldívar-Guerra ,
Odilia Pérez-Camacho  and
Maricela García-Zamora
Ramiro Infante-Martínez*
Affiliation:
Centro de Investigación en Química Aplicada, Saltillo, Coahuila. México
Enrique Saldívar-Guerra
Affiliation:
Centro de Investigación en Química Aplicada, Saltillo, Coahuila. México
Odilia Pérez-Camacho
Affiliation:
Centro de Investigación en Química Aplicada, Saltillo, Coahuila. México
Maricela García-Zamora
Affiliation:
Centro de Investigación en Química Aplicada, Saltillo, Coahuila. México
*
*To whom correspondence should be addressed: [email protected]
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Abstract

An experimental study oriented to gather kinetic modelling data in the ethylene polymerization via metallocenes is reported. Also is illustrated the employment of two methods for determination of kinetic behavior and the instantaneous activity of Ziegler-Natta catalysts in the slurry polymerization of ethylene. The theoretical basis for both methods is described as well as the required instrumentation for its implantation at a laboratory level. An experimental program of polymerization with two different metallocenic systems was executed, showing that the direct (measurement of ethylene flow) as well as the calorimetric method (based on energy balances) give equivalent high quality information on the kinetic performance of the catalyst.

Keywords

sensorkineticscalorimetrypolymerization
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1767: Symposium 5C – New Trends in Polymer Chemistry and Characterization , 2015 , pp. 11 - 16
Copyright
Copyright © Materials Research Society 2015 

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References

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