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Electronic Properties of some Ternary and Quaternary Oxides of the VIII B and I B Transition Elements: Application to High Tc Superconductivity

Published online by Cambridge University Press:  21 February 2011

M. Pouchard ,
J-C. Grenier ,
J-P. Doumerc ,
G. Demazeau ,
J-P. Chaminade ,
A. Wattiaux ,
P. Dordor  and
P. Hagenmuller
M. Pouchard
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
J-C. Grenier
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
J-P. Doumerc
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
G. Demazeau
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
J-P. Chaminade
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
A. Wattiaux
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
P. Dordor
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
P. Hagenmuller
Affiliation:
Laboratoire de Chimie du Solids du C.N.R.S., Univernité de BORDEAUX I, 33405 TALENCE-Cédex, FRANCE
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Abstract

In the scope of the Goodenough model, a brief review of the electronic properties of some 3d transition elements (M = Fe, Co, Ni and Cu ) is given; the main relevant electronic and structural parameters are emphasized. Then a special attention is focussed on N/(N−1) and N/(N−2) electron mixed valence compounds.

Finally some particular features of copper are discussed and their relevance to high Tc superconductors is pointed out:

-the srong covalency of Cu-O bondings involving a possible delocalization of the hole between trivalent copper and oxygen,

-the existence of low and high spin electronic configurations for CuIII,

-the disproportionation of Cu2+ and its role in the formation of hole pairs,

Cu-O distances very close for the three successive oxidation states of copper favouring the disproportionation process.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 156: Symposium M – High Temperature Superconductors: Relationships Between Properties, Structure, and Solid State Chemistry , 1989 , 13
Copyright
Copyright © Materials Research Society 1989

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References

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