Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-16T16:10:43.220Z Has data issue: false hasContentIssue false
  • English
  • Français

Electrodeposition of Cu2ZnSnS4 Thin Films Using Ionic Liquids

Published online by Cambridge University Press:  21 March 2011

C.P. Chan ,
H. Lam ,
K.Y. Wong  and
C. Surya
C.P. Chan
Affiliation:
Department of Electronic and Information Engineering and Photonics Research CentreThe Hong Kong Polytechnic University, Hong Kong, China
H. Lam
Affiliation:
Department of Electronic and Information Engineering and Photonics Research CentreThe Hong Kong Polytechnic University, Hong Kong, China
K.Y. Wong
Affiliation:
Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, China
C. Surya*
Affiliation:
Department of Electronic and Information Engineering and Photonics Research CentreThe Hong Kong Polytechnic University, Hong Kong, China
*
Corresponding author
Get access

Abstract

We report the growth of Cu2ZnSnS4 (CZTS) thin films by electrodeposition in ionic liquid. Sulfurization was performed in elementary sulfur vapor environment at 450°C for 2 hours. The X-ray diffraction analysis indicated that the film has a stannite structure with preferred grain orientation along (112). Photo-absorption measurement of the sample was performed from 500 nm to 990 nm. It is found that the energy bandgap of the film is about 1.49eV and the absorption coefficient is found to be of the order of 104cm-1.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1123: Symposium P – Photovoltaic Materials and Manufacturing Issues , 2008 , 1123-P05-06
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Klenk, R. and Lux-Stiner, M. Ch., “Chalcopyrite based solar cells,” Thin Film Solar Cells, ed. Poortmans, J. and Arkhipov, V. (Wiley, 2006) pp.236–275.Google Scholar
2. Repins, I., Contreras, M. A., Egaas, B., DeHart, C., Scharf, J., Perkins, C. L., To, B. and Noufi, R., Progress in Photovoltaics: Research and Applications 16, 235 (2008).Google Scholar
3. Marsh, K. N., Boxall, J. A. and Lichtenthaler, R., Fluid Phase Equilibria 219, 93–98 (2004).Google Scholar
4. Abedin, S. Z. EI. and Endres, F., ChemPhysChem 7, 58–61 (2005).Google Scholar
5. Katagiri, H., Saitoh, K. and Washio, T., Solar Energy Materials & Solar cells 65, 141–148 (2001).Google Scholar