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Efficient Second Harmonic Generation in Hydrazone, Derivatives of Substituted Aromatic Aldehydes

Published online by Cambridge University Press:  25 February 2011

Richard S. Potember ,
Robert C. Hoffman  and
Karen A. Stetyick
Richard S. Potember
Affiliation:
The Johns Hopkins University, Applied Physics, Johns Hopkins Road, Laurel, MD 20723-6099
Robert C. Hoffman
Affiliation:
The Johns Hopkins University, Applied Physics, Johns Hopkins Road, Laurel, MD 20723-6099
Karen A. Stetyick
Affiliation:
The Johns Hopkins University, Applied Physics, Johns Hopkins Road, Laurel, MD 20723-6099
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Abstract

Hydrazone, 1,1-dimethylhydrazone, methylhydrazone, phenylhydrazone and p-nitrophenyl hydrazone derivatives of substituted aromatic aldehydes were prepared and screened for second harmonic generation using the Kurtz powder technique. One compound, 4-nitro-3-methoxybenzaldehyde hydrazone exhibited a second harmonic signal up to 32 times that of ammonium dihydrogen phosphate (ADP) and 4-nitrobenzaldehyde hydrazone exhibited a second harmonic signal five times higher than previously reported, up to 40 times that of ADP. 3-methyl-4-nitrobenzaldehyde hydrazone, 4-nitrobenzaldehyde phenylhydrazone, 1-naphthaldehyde phenylhydrazone, 1-pyrenecarboxaldehyde phenylhydrazone exhibited second harmonic signals 25, 2.5, 5 and 20 times that of an ADP standard.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 173: Symposium Q – Advanced Organic Solid State Materials , 1989 , 697
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

[1] Levine, B. F., Bethea, C. G., Thurmond, C. D., Lynch, R. T., and Bernstein, J. L., “An Organic Crystal with an Exceptionally Large Optical Second Harmonic Coefficient: 2-Methyl-4-Nitro Aniline”, J. Appl. Phys. 50, 2523(1979).CrossRefGoogle Scholar
[la] Halbout, J., Blit, S., Donaldson, W., and Tang, C. L., IEEE Journal of Quantum Electronics, Vol. QE–15, No. 10 (1979) 1176.Google Scholar
[2] Baldwin, G.C., An Introduction to Nonlinear Optics. Plenum Press: New York, 81 (1969).CrossRefGoogle Scholar
[3] Oudar, J. L., J. Chem Phys. 67, 446 (1977).Google Scholar
[4] Kurtz, S. and Perry, T. T., “A Powder Technique for the Evaluation of Nonlinear Optical Materials,” J. Appl. Phys. 39, 3798 (1968).Google Scholar
[5] Dewar, M. J. S., J. Chem. Soc., 2329 (1950).Google Scholar
[6] Davydov, B. L., Kotocshchikov, S. G., Nefedov, V. A., “New Nonlinear Organic Materials for Generation of Second Harmonics of Neodymium Laser Radiation,” Sov. J. Quantum Electronics (Eng. Trans.) 7, 129 (1977).Google Scholar
[6a] Lupo, D., Prass, W., Sceunemann, U., and Ledoux, I., J. Opt. Soc. Am. B, (5) 2, (1988) 300.CrossRefGoogle Scholar
[7] Beilstein, “Beilstein’s Handbuch der Organischen Chemie,” 7, 256.Google Scholar