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Effect of high pressure on glass transition in Zr-Ti-Cu-Ni-Be bulk metallic glass
Published online by Cambridge University Press: 11 February 2011
Abstract
A new method is developed to directly exhibit glass transition in Zr-Ti-Cu-Ni-Be bulk glass-forming alloy under high pressure in metallic glass. Via the method, we derive an increase of glass transition temperature, Tg with pressure of 5.6 K/GPa, and a formation volume (ΔVf) of 6.5 Å3 for diffusion and the migration volume (ΔVm) of 6.5 Å3. The glass transition under high pressure is simulated based on the free-volume theory, and the simulations are consistent with the experimental observations.
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- Copyright © Materials Research Society 2003
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