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Diffusion Cells for Integrating Temperature and Humidity Over Long Periods of Time

Published online by Cambridge University Press:  22 February 2011

Fred Trembour
Affiliation:
U.S. Geological Survey, D.F.C., M.S. 963, Box 25046, Denver, CO. 80225
Franklin L. Smith
Affiliation:
U.S. Geological Survey, D.F.C., M.S. 963, Box 25046, Denver, CO. 80225
Irving Friedman
Affiliation:
U.S. Geological Survey, D.F.C., M.S. 963, Box 25046, Denver, CO. 80225
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Abstract

The rate of many processes, including the diffusion of water into rhyolitic volcanic glass (obsidian), as well as the racemization of amino acids is temperature dependent, and a knowledge of temperatures integrated over time periods of at least a year is necessary to quantify these processes. The construction and properties of simple devices consisting of small plastic containers that change weight at a rate that is a function of temperature and the activity of water will be described. The cells function because water diffuses through the plastic across a constant vapor-pressure gradient. This vapor-pressure gradient is maintained constant between the substances within the cell and the materials outside the cell. The plastic cells are usually filled with water and surrounded by a dehydrating agent, such as silica gel. A better arrangement is to fill the cell with a mixture of solid sodium chloride (NaCl) and a saturated solution of NaCl, and to surround the cell with pure water. A number of plastics have been investigated, including polycarbonate, polystyrene, tefzel, polyallomer, and methacrylate. The cells have been sealed by various methods including screw caps, room-temperature vulcanizingsilicone rubber sealant, and rubber stoppers. The final design consists of a small cell made of a polycarbonate plastic centrifuge tube containing solid NaCl plus NaCl-saturated solution sealed with a rubber stopper and placed in a polypropylene tube containing pure water. Our aim has been to develop cells that are sufficiently sensitive to yield a precision of ±0.2° C when exposed for one year at temperatures that range from 0° to 40°, and that will fit into metal fittings that can be screwed into standard 3/4-inch plastic water pipe (approximately 1 inch outside diameter).

Type
Research Article
Copyright
Copyright © Materials Research Society 1988

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References

1 Ambrose, W., Advances in Obsidian Glass Studies edited by Taylor, R.E.(Noyes Press, New Jersey, 1978) pp 110114 Google Scholar
2 Trembour, F.W., Friedman, I., Jurceka, F.J., Smith, F.L., J. Atmos. & Ocean Tech. 3, 186190 (1986)2.0.CO;2>CrossRefGoogle Scholar