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Diffraction Symmetry in Crystalline, Close-Packed C60

Published online by Cambridge University Press:  28 February 2011

R. M. Fleming ,
T. Siegrist ,
P. M. Marsh ,
B. Hessen ,
A. R. Kortan ,
D. W. Murphy ,
R. C. Haddon ,
R. Tycko ,
G. Dabbagh  and
A. M. Mujsce
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R. M. Fleming
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
T. Siegrist
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
P. M. Marsh
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
B. Hessen
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
A. R. Kortan
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
D. W. Murphy
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
R. C. Haddon
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
R. Tycko
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
G. Dabbagh
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
A. M. Mujsce
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
M. L. Kaplan
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
S. M. Zahurak
Affiliation:
AT&T Bell Laboratories, Murray Hill, New Jersey 07974
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Abstract

We have grown crystals of the carbon structure C60 by sublimation. In contrast to solution-grown crystals, the sublimed crystals have long range order with no evidence of solvent inclusions. Sublimed C60 forms three dimensional, faceted crystals with a close-packed, face-centered cubic unit cell. We have refined a crystal structure using the “soccer ball” model of the C60 molecule. The results indicate that the C60 molecule has the expected spherical shape, however the data are not sufficiently accurate to unambiguously determine atomic positions.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 206: Symposium G – Clusters and Cluster-Assembled Materials , 1990 , 691
Copyright
Copyright © Materials Research Society 1991

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References

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