Hostname: page-component-78c5997874-4rdpn Total loading time: 0 Render date: 2024-11-20T00:49:13.906Z Has data issue: false hasContentIssue false
  • English
  • Français

Dielectric Characterization of Polyceram Films

Published online by Cambridge University Press:  28 February 2011

G. Teowee ,
J.M. Boulton ,
H.H. Fox ,
A. Koussa ,
T. Gudgel  and
D.R. Uhlmann
G. Teowee
Affiliation:
Department of Materials Science and Engineering, University of Arizona, Tucson, AZ 85721.
J.M. Boulton
Affiliation:
Department of Materials Science and Engineering, University of Arizona, Tucson, AZ 85721.
H.H. Fox
Affiliation:
Department of Materials Science and Engineering, University of Arizona, Tucson, AZ 85721.
A. Koussa
Affiliation:
Department of Materials Science and Engineering, University of Arizona, Tucson, AZ 85721.
T. Gudgel
Affiliation:
Department of Materials Science and Engineering, University of Arizona, Tucson, AZ 85721.
D.R. Uhlmann
Affiliation:
Department of Materials Science and Engineering, University of Arizona, Tucson, AZ 85721.
Get access

Abstract

Polycerams are an emergent class of hybrid, multifunctional materials which combine the properties of organic and inorganic materials. Films have been prepared from silicon alkoxides and reactive, functionalized polymers such as triethoxysilyl modified polybutadiene (MPBD), (N-triethoxysilylpropyl)O polyethylene oxide urethane (MPEOU) and trimethoxysilylpropyl substituted polyethyleneimine (MPEI). Characterization of dielectric constant and tan δ of the films has been carried out over a range of frequency from 500 Hz to 100 kHz; and the results are used to consider the potential of Polycerams as dielectric materials.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 180: Symposium A – Better Ceramics Through Chemistry IV , 1990 , 407
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Schmidt, H. in Better Ceramics Through Chemistry, edited by Brinker, C.J., Clark, D.E. and Ulrich, D.R. (Mater. Res. Soc. Proc. 32, 1984) pp. 681–691.Google Scholar
2. Schmidt, H. and Seiferling, B. in Better Ceramics Through Chemistry II, edited by Brinker, C.J., Clark, D.E. and Ulrich, D.R. (Mater. Res. Soc. Proc. 73 1986) pp. 739–750.Google Scholar
3. Parkhurst, C.S., Doyle, W.F., Silverman, L.A., Singh, S., Anderson, M.P., McClurg, D., Wnek, G.E. and Uhlmann, D.R., ibid, pp. 769–773.Google Scholar
4. Huang, H.H., Orler, B. and Wilkes, G.L., Macromolecules 20, 1322 (1987).Google Scholar
5. Glaser, R.H. and Wilkes, G.L., Polymer Bull., 19, 51 (1988).Google Scholar
6. Schmidt, H., in Sol-Gel Science and Technology, edited by Aegerter, M.A., Jafelicci, M. Jr., Souza, D.F. and Zanotto, E.D. (World Scientific Publishing, Singapore, 1989), p. 432.Google Scholar
7. Schmidt, H., DVS-Berichte 110, 54 (1988).Google Scholar
8. Boulton, J.M., Fox, H.H., Neilson, G.F. and Uhlman, D.R. paper entitled “Synthesis and Structural Characteristics of Polycerams” presented at this proceedings.Google Scholar
9. Brinker, C.J., Roth, E.P., Scherer, G.W. and Tallant, D.R., J. Non-Cryst. Solids 71, 171 (1985).Google Scholar
10. Jouscher, A.K., Dielectric Relaxation in Solids, Chelsea Dielectric Press, London (1983).Google Scholar