Hostname: page-component-78c5997874-mlc7c Total loading time: 0 Render date: 2024-11-16T17:18:34.151Z Has data issue: false hasContentIssue false
  • English
  • Français

Development of Boron Cage Compound Nanocomposite Elastomers

Published online by Cambridge University Press:  31 January 2011

Eric Allen Eastwood ,
Daniel Edward Bowen  and
Mark W. Lee
Eric Allen Eastwood
Affiliation:
[email protected][email protected], Honeywell Federal Manufacturing & Technologies, Organic Materials and Polymer Production, Kansas City, Missouri, United States
Daniel Edward Bowen
Affiliation:
[email protected], Honeywell Federal Manufacturing & Technologies, Organic Materials and Polymer Production, Kansas City, Missouri, United States
Mark W. Lee
Affiliation:
[email protected], University of Missouri-Columbia, Department of Radiology, International Institute of Nano and Molecular Medicine, Columbia, Missouri, United States
Get access

Abstract

A wide variety of nanofillers of varying compositions have been used to create polymer nanocomposites, including tubes, wires, fibers, sheets, and particles. A new class of compounds has been identified for use as nanofillers, boron cage compounds. Boron cage compounds are discrete, icosahedral closed cage molecules of high boron content and examples include carboranes and dodecaborate salts. Several chemically modified boron cage compounds have been incorporated into polyolefin elastomers, such as poly(ethylene-co-vinyl acetate), poly(ethylene-co-vinyl acetate-co-vinyl alcohol), poly(ethylene-co-ethyl acrylate), and poly(ethylene-co-octene), among others. The resulting thermal and thermomechanical properties were evaluated in order to determine when plasticization and reinforcement occur to better understand the chemical structure/physical property relationships. Materials with a wide range of properties were produced, however under certain conditions, advanced materials were created with high boron contents, improved thermal stability, mechanical strength, and significant reinforcement.

Keywords

nanostructureadditivespolymer
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1239: Symposium VV – Micro- and Nanoscale Processing of Biomaterials , 2009 , 1239-VV05-06
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1(a) Schulz, M. J., Kelkar, A. D. & Sundaresan, M. J. Nanoengineering of Structural, Functional, and Smart Materials. (CRC Press Taylor & Francis Group, Boca Raton, 2006) pp. 225–245.Google Scholar
2(a) Eastwood, E. A., Bowen III, D. E., Lee, M. W., and Hawthorne, M. F. “Development of Boron Cage Compound Nanocomposite Elastomers” SAMPE FALL Technical Conference Proceedings. Wichita, KS, 2009. (b) Bowen III, D. E., Eastwood, E. A., Lee, M. W., and Hawthorne, M. F. “Development of Epoxy and Urethane Boron Cage Compound Nanocomposites” SAMPE FALL Technical Conference Proceedings. Wichita, KS, 2009.Google Scholar
3(a) Wunderlich, J. A. and Lipscomb, W. N. J. Am. Chem. Soc. 82, 4427 (1960). (b) Longuet-Higgins, H. C. & Roberts, M. de V. Proc. R. Soc. London A 230, 110 (1955). (d) Hawthorne, M. Frederick Special Publication No. 201; Royal Society of Chemistry 82, 261 (1997). (e) Gomez, F. A., & Hawthorne, M. F. J. Org. Chem. 57, 1384 (1992). (f) Gomez, F. A., Johnson, S. E., & Hawthorne, M. F. J. Am. Chem. Soc. 113, 5915 (1991). (g) Heying, T. L., Ager, J. W., Clark, Jr., S. L., Alexander, R. P., Papetti, S., Reid, J. A., & Trotz, S. I. Inorg. Chem. 2, 1097 (1963).Google Scholar
4(a) Choi, J., Harcup, J., Yee, A. F., Zhu, Q., & Laine, R. M. J. Am. Chem. Soc. 123, 11420 (2001). (b) Joshi, M. & Butola, B. S. J. Macromol. Sci., Part C: Poly. Rev. 44, 389 (2004). (c) Kropka, J. M., Sakai, V. G., & Green, P. F. Nano Let. 8, 1061 (2008). (d) Kropka, J. M., Putz, K. W., Pryamitsyn, V., Ganesan, V., & Green, P. F. Macromolecules 40, 5424 (2007).Google Scholar
5 Eastwood, Eric. “VCE Replacement: Synthesis of VCEs with New Formulations” Technical Report from Kansas City Plant. KCP-613-8202, 2006.Google Scholar
6(a) Rudin, Aldred. The Elements of Polymer Science and Engineering (Academic Press, San Diego, 1982) pp. 417.Google Scholar