Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-25T17:51:08.970Z Has data issue: false hasContentIssue false

Design and Synthesis of Novel Side-Chain Polyquinolines and Polyimides for Second-Order Nonlinear Optics

Published online by Cambridge University Press:  10 February 2011

A. K-Y. Jen
Affiliation:
ROI Technology, Optical Materials Division, 2000 Cornwall Road, Monmouth Junction, NJ 08852
T.-A. Chen
Affiliation:
ROI Technology, Optical Materials Division, 2000 Cornwall Road, Monmouth Junction, NJ 08852
Y.-M. Cai
Affiliation:
ROI Technology, Optical Materials Division, 2000 Cornwall Road, Monmouth Junction, NJ 08852
Get access

Abstract

Novel approaches to second-order nonlinear optical (NLO) side-chain polyquinolines and polyimides are described. The syntheses and the characterization of the polymers are detailed. The electro-optical coefficients (r33), temporal stability of dipole alignment, and other physical properties of the NLO polymers are presented.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Wong, K. Y.; Jen, A. K-Y. J. Appl. Phys., 1994, 75, 3308.Google Scholar
2. Xu, C.; Wu, B.; Dalton, L. R.; Shi, Y.; Ranon, P. M.; Steier, W. H. Macromolecules, 1991,24, 5421.Google Scholar
3. Park, J.; Marks, T.; Yang, J.; Wong, G. K. Chem. Mater., 1990, 2, 229.Google Scholar
4. Zysset, B.; Ahlheim, M.; Stahelin, M.; Lahr, F.; Pretre, P.; Kaatz, P.; Gunter, P. Proc. SPIE, 1993, 2025, 70.Google Scholar
5. Becker, M.; Sapochak, L.; Ghosen, R.; Xu, C.; Dalton, L. R.; Shi, Y.; Steier, W. H.; Jen, A. K-Y. Chem. Mater., 1994, 6, 104.Google Scholar
6. Peng, Z.; Yu, L. Macromolecules, 1994, 27, 2638.Google Scholar
7. Jen, A. K-Y.; Drost, K. J.; Cai, Y.; Rao, V. P.; Dalton, L. R. J. Chem. Soc., Chem. Commun., 1994, 965.Google Scholar
8. Crumpler., E. T.; Reznichenko, J. L.; Li, D.; Marks, T. J.; Lin, W.; Lundquist, P. M.; Wong, G. K. Chem. Mater. 1995, 7, 596.Google Scholar
9. Liang, Z.; Dalton, L. R.; Garner, S. M.; Kalluri, S.; Chen, A.; Steier, W. H. Chem. Mater. 1995, 7, 941.Google Scholar
10. (a) Verbiest, T.; Burland, D. M.; Jurich, M. C.; Lee, V. Y.; Miller, R. D.; Volkson, W. Science 1995, 268, 1604. (b) Miller, R. D.; Burland, D. M.; Jurich, M.; Lee, V. Y.; Moylan, C. R.; Thackara, J. I.; Twieg, R. J.; Verbiest, T.; Volksen, W. Macromolecules 1995, 28, 4970.Google Scholar
11. (a) Yu, D.; Gharavi, A.; Yu, L. Macromolecules, 1995, 28, 784. (b) Yu, D.; Yu, L. Macromolecules, 1994, 27, 6718.Google Scholar
12. (a) Jen, A. K-Y.; Liu, Y. J.; Cai, Y.; Rao, V. P.; Dalton, L. R. J. Chem. Soc., Chem. Commun., 1994, 2711. (b) Jen, A. K-Y.; Cai, Y.; Drost, K. J.; Liu, Y. J.; Rao, V. P.; Chen, T.- A.; Mininni, R. M.; Kenney, J. T. Proceedings of the Am. Chem. Soc., PMSE, 1995, 72, 213. (c) Chen, T.-A.; Jen, A. K-Y.; Cai, Y. J. Am. Chem. Soc. 1995, 117,7295.Google Scholar
13. Ho, B.-C.; Liu, Y.-S.; Lee, Y.-D. J.App. Polym. Sci., 1994, 53, 1513.Google Scholar
14. Mitsunobu, O. Synthesis, 1981, January, 1.Google Scholar
15. Stille, J. K. Macromolecules 1981, 14, 870880, and references therein.Google Scholar
16. (a) Agrawal, A. K.; Jenekhe, S. A. Macromolecules 1993, 26, 895. (b) Agrawal, A. K.; Jenekhe, S. A.; Vanherzeele, H.; Meth, J. S. J. Phys. Chem. 1992, 96, 2837. (c) Agrawal, A. K.; Jenekhe, S. A. Chem. Mater. 1992, 4, 95.Google Scholar
17. Cai, Y. M.; Jen, A. K-Y. Appl. Phys. Lett. 1995, 67, 299.Google Scholar
18. Teng, C. C.; Men, H. T. Appl. Phys. Lett. 1990,56, 1754.Google Scholar