Hostname: page-component-cd9895bd7-dk4vv Total loading time: 0 Render date: 2024-12-27T02:28:20.939Z Has data issue: false hasContentIssue false
  • English
  • Français

Covalent coupling of ionic liquid to carbon nanotubes: preparation and tribological properties

Published online by Cambridge University Press:  04 June 2014

Triinu Taaber ,
Kaija Põhako-Esko ,
Urmas Joost ,
Kadi Külasalu ,
Mikk Antsov ,
Maksim Antonov ,
Renno Veinthal ,
Kristjan Saal ,
Rünno Lõhmus  and
Uno Mäeorg
Triinu Taaber
Affiliation:
University of Tartu, Institute of Chemistry, 14a Ravila St.,50411, Tartu, Estonia. University of Tartu, Institute of Physics and Estonian Nanotechnology Competence Center,142 Riia St., 51014, Tartu, Estonia.
Kaija Põhako-Esko
Affiliation:
University of Tartu, Institute of Chemistry, 14a Ravila St.,50411, Tartu, Estonia. University of Tartu, Institute of Physics and Estonian Nanotechnology Competence Center,142 Riia St., 51014, Tartu, Estonia.
Urmas Joost
Affiliation:
University of Tartu, Institute of Physics and Estonian Nanotechnology Competence Center,142 Riia St., 51014, Tartu, Estonia.
Kadi Külasalu
Affiliation:
University of Tartu, Institute of Physics and Estonian Nanotechnology Competence Center,142 Riia St., 51014, Tartu, Estonia.
Mikk Antsov
Affiliation:
University of Tartu, Institute of Physics and Estonian Nanotechnology Competence Center,142 Riia St., 51014, Tartu, Estonia.
Maksim Antonov
Affiliation:
Tallinn University of Technology, Department of Mechanical Engineering, 5 Ehitajate tee St., 19086, Tallinn, Estonia
Renno Veinthal
Affiliation:
Tallinn University of Technology, Department of Mechanical Engineering, 5 Ehitajate tee St., 19086, Tallinn, Estonia
Kristjan Saal
Affiliation:
University of Tartu, Institute of Physics and Estonian Nanotechnology Competence Center,142 Riia St., 51014, Tartu, Estonia.
Rünno Lõhmus
Affiliation:
University of Tartu, Institute of Physics and Estonian Nanotechnology Competence Center,142 Riia St., 51014, Tartu, Estonia.
Uno Mäeorg
Affiliation:
University of Tartu, Institute of Chemistry, 14a Ravila St.,50411, Tartu, Estonia.
Get access

Abstract

A new approach for functionalising oxidised MWCNTs using hydroxylated imidazolium bromide via esterification reaction is reported. The bromide anion of a functionalised MWCNTs was exchanged with bis(trifluoromethanesulfonyl) imide (TFSI) through a metathesis reaction to improve its solubility in the IL medium. Composite was characterized with IR, XPS, EDX and TGA analysis, which clearly confirmed that the MWCNTs were functionalized with IL. For potential application as lubricant, the tribological properties of the IL-functionalised MWCNTs (MWCNT-IL) were also evaluated. It was confirmed that even low concentrations of MWCNT-IL composite in ILs causes a significant improvement in the anti-wear and friction properties.

Keywords

chemical synthesislubricanttribology
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1707: Symposium UU – Semiconductor Nanowires—Synthesis, Properties and Applications , 2014 , mrss14-1707-uu06-30
Copyright
Copyright © Materials Research Society 2014 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Fukushima, T., Kosaka, A., Ishimura, Y., Yamamoto, T., Takigawa, T., Ishii, N., Aida, T., Science 300, 2072–2074 (2003).CrossRefGoogle Scholar
Shin, J.Y., Premkumar, T., Geckler, K.E., Chem. Eur. J. 14, 20, 6044–6048 (2008).CrossRefGoogle Scholar
Jeong, Y.N., Choi, M.Y., Choi, H.C., Electrochimica Acta. 60, 78–84 (2012).CrossRefGoogle Scholar
Wang, B., Wang, X., Lou, W., Hao, J., J. Phys. Chem. C. 114, 19, 8749–8754 (2010).CrossRefGoogle Scholar
Abuilaiwi, F.A., Laoui, T., Al-Harthi, M., Atieh, M.A.. Arab. J. Sci. Eng. 35, 37–46 (2010).Google Scholar
Inamuddin, A.Muhammad. Green Solvents II. Springer, (2012).Google Scholar
Chong, M., Heuft, M.A., Rabbat, P., J. Org. Chem. 65, 18, 5837–5838 (2000).CrossRefGoogle Scholar
Shaplov, A.S., Goujon, L., Vidal, F., Lozinskaya, E.I., Meyer, F., Malyshkina, I.A., Chevrot, C., Teyssie, D., Odinets, I.L., Vygoskii, Y.S., J.Polym.Sci., Part A: Polym.Chem. 47,17, 4245–4266 (2009).CrossRefGoogle Scholar
Li, Y., Zhang, X., Shen, L., Luo, J., Tao, X., Liu, F., Xu, G., Wang, Y., Geise, H.J., Tendeloo, G.V., Chem. Phys. Lett. 398, 276–282 (2004).CrossRefGoogle Scholar
Põhako-Esko, K., Taaber, T., Saal, K., Lõhmus, R., Kink, I., Mäeorg, U., Synth.Commun.43,1–7 (2013).CrossRefGoogle Scholar
Katsyuba, S.A., Dyson, P.J., Vandyukova, E.E., Chernova, A.V., Vidiš, A., Helv. Chim. Acta. 87, 10, 2556–2565 (2004).CrossRefGoogle Scholar
Ferlauto, A.S., De Florio, D.Z., Fonseca, F.C., Esposito, V., Muccillo, R., Traversa, E., Laderia, L.O., Appl. Phys. A. 84, 271–276 (2006).CrossRefGoogle Scholar
Cremer, T., Killian, M., Gottfried, J.M., Paape, N., Wasserscheid, P., Maier, F., Steinrück, H-P., Chem. Phys. Chem. 9, 2185 – 2190 (2008).CrossRefGoogle Scholar
Datsyuk, V., Kalyva, M., Papagelis, K., Tasis, D., Kallitsis, I., Galiotis, C., Carbon 46, 840 (2008).CrossRefGoogle Scholar
Qu, J., Blau, P.J., Dai, S., Luo, H., Meyer, H.M., Tribol Lett 35,181–189 (2009).CrossRefGoogle Scholar
Greenberg, R., Halperin, G., Etsion, I., Tenne, R., Tribol. Lett. 17, 179–186 (2004).CrossRefGoogle Scholar
Song, Y., Xia, Y., Liu, Z., Tribol. T. 55, 6, 738–746 (2012).CrossRefGoogle Scholar